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    基于深部煤炭地下气化的CO2地质封存潜力及研究进展

    Potential and research progress of CO2 geological storage based on deep coal underground gasification

    • 摘要: 深部煤炭地下气化耦合CO₂封存(UCG-CCS)是实现煤炭清洁开发与碳减排的关键技术,在提高燃空腔利用率的同时,将CO2进行地质封存,具有注入性好、密闭性复杂、节约运输成本和埋存潜力巨大等特点,近年来成为CO2封存研究的热点。从机理研究、稳定性评价、封存效能及泄漏监测4个维度系统综述其研究进展:① 深部煤炭地下气化燃空腔深度、温度有利于超临界CO2封存,燃空腔的高渗透性可保证CO2良好注入;气化残焦、灰渣和垮落的岩石具有吸附和矿化能力;与燃空腔内咸水层的长期相互作用有利于CO2溶解封存。② 空腔密闭性与气化煤层厚度、气化面宽度、留存煤柱宽度、地层深度和地质构造等因素有关,通过气化炉结构综合设计确保密闭性;需控制CO2注入压力避免突破盖层压力;CO2地质封存长期运移依赖于长周期数值模拟及工程观测;注入井和生产井是CO2泄漏的重要途径。③ 地下气化燃空腔封存能力取决于燃空腔形貌、产气量和产气组分,目前亟需一种准确的煤炭地下气化燃空腔封存CO2封存能力评价模型。④ 泄漏监测是工程封存CO2必不可少的风险管控环节,CO2封存需长期监测地表变形、井筒泄漏及污染物迁移,但面临地层非均质性、高温腐蚀、信号衰减等挑战,需构建多相渗流模型及环境可持续性指数评估体系保障安全。

       

      Abstract: Deep coal underground gasification coupled CO2 storage (UCG-CCS) is a key technology to achieve clean coal development and carbon emission reduction. While improving the utilization rate of combustion cavity, the geological storage of CO2 has the characteristics of good injection, complex sealing, saving transportation cost and great storage potential, etc., and has become a hot spot in CO2 storage research in recent years. In this paper, the research progress is systematically reviewed from four dimensions: mechanism research, stability evaluation, storage efficiency and leakage monitoring: ① The depth and temperature of deep coal underground gasification combustion cavity are conducive to supercritical CO2 storage, and the high permeability of combustion cavity can ensure good CO2 injection; Gasification residue, ash and caved rock have adsorption and mineralization ability. The long-term interaction with the salt water layer in the combustion cavity is conducive to CO2 dissolution and storage. ② The cavity tightness is affected by multiple factors, and is related to the thickness of the gasification coal seam, the width of the gasification surface, the width of the retained coal pillar, the depth of the formation and the geological structure, etc. The comprehensive design of the gasifier structure ensures the tightness; The CO2 injection pressure should be controlled to avoid breaking through the cap pressure. The long-term transport of CO2 geologic storage depends on the long-period numerical simulation and engineering observation. Injection Wells and production Wells are important ways of CO2 leakage. ③ The storage capacity of underground coal gasification depends on the shape of the combustion cavity, gas production and gas production components. At present, an accurate CO2 storage capacity evaluation model for underground coal gasification and gas storage is urgently needed. ④ Leakage monitoring and environmental risk assessment is an essential risk control link for engineering CO2 storage. CO2 storage requires long-term monitoring of surface deformation, wellbore leakage and pollutant migration, but faces challenges such as formation heterogeneity, high-temperature corrosion, signal attenuation, etc., and needs to build a multiphase seepage model and environmental sustainability index evaluation system to ensure safety.

       

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