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Generation characteristics of tar in fluidized bed coal gasification

2022 No. 04
743
299
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Authors:
DENG Shangzhi
JIANG Huawei
LI Weiqiang
YUAN Ye
GUO Qingjie
WANG Cuiping
Unit:
College of Mechanical and Electrical Engineering,Qingdao University;State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering,Ningxia University;College of Civil Engineering and Architecture,Shandong University of Science and Technology
Abstract:

Tar generated during the coal gasification may condense at low temperature,thus blocking the process equipment,leading to the pollution of the equipment,and increasing operating costs. The adjustment of operation parameters based on the tar generation characteristics would be conducive to reduce the original tar emission from a gasifier and reduce the cost of tar removal. In order to obtain the generation characteristics of tar in fluidized bed coal gasification,the effects of parameters such as bed temperature,air equivalent ratio,superficial gas velocity,coal particle size and water content,upon the generation amount of tar in the product gas were studied by fluidized bed reactor. The results show that increasing temperature or air equivalent ratio is beneficial to the decrease of tar mass concentration,but the effects are both limited. When the apparent gas velocity ug in the furnace increases from 0.19 to 0.33 m/s,more intensified contact and mixing between gas and solids improve the effects of heat transfer and mass transfer in the gasifier and promote the thermal decomposition of tar produced. However,as the bubbling fluidization transits to turbulent fluidization,the contact and mixing between gas and solids are no longer significantly enhanced,and the tar mass concentration thus changes little. The small diameters of coal particles can improve the chemical reaction rate and promote the thermal decomposition of tar. However,at a certain fluidization gas velocity,the smaller the gasification feedstocks is,the more it is easily distributed on the bed,which weakens the heat transfer between coals and bed materials,and shortens the residence time of tar in the furnace,leading to the rise of tar mass concentration. The tar mass concentrations in the product gas of coal gasification under different moisture contents have obvious difference. Neither too high nor too low for water content are beneficial to the reduction of tar generation.

Keywords:
coal gasification
generation characteristics of tar
fluidized bed
superficial gas velocity
coal particle size
moisture content
heat and mass transfer
Citation format:
邓尚致(1995—),男,江西赣州人,硕士研究生。E-mail:shangzhiD@yeah.net
通讯作者:姜华伟(1984—),男,山东荣成人,讲师,博士。E-mail:jianghuawei@tsinghua.org.cn
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  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    Technology Research Center

  • Editor in Chief

    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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