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Compression heat pump in CO2-MDEA/PZ system for post combustioncarbon dioxide capture

2024 No. 10
330
124
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Authors:
YU Miao
XU Yanjie
FANG Mengxiang
NIE Taotao
WANG Tao
WU Haiqian
ZENG Weiqiang
Unit:
Xizi Clean Energy Equipment Manufacturing Co.,Ltd.
School of Civil Engineering and Architecture,College of EnergyEngineering,Zhejiang Sei-Tech University
Abstract:

The high investment,high energy consumption for absorbent regeneration,and high operational costs of current chemical-based CO2 capture systems pose major obstacles to their large-scale application. To recover the latent and sensible heat in the steam at thetop of the stripper and facilitate the desorption reaction,a process simulation model for CO2 capture using organic amines based oncompression heat pump technology was established using Aspen plus software. This primarily explored the impact of stripper bottompressure,rich solvent temperature entering the stripper organic working fluid vaporization rate,and process flow on the CO2 regenerationprocess. The results demonstrate that the heating coefficient of the organic working fluid R123 is higher than that of R141b and R245fa.Specifically,its coefficient of performance (COP) reaches as high as 2.35,while its exhaust temperature is lower compared to R141b andR245fa. Additionally,the exhaust temperature of R123 is lower compared to that of R141b and R245fa. The compression-type heat pumpemploys R123 as the circulating process medium,and the heat recovered by the heat pump is utilized to heat the post-heat-exchange richsolution in the lean/rich solution heat exchanger,thereby reducing the energy consumption for the regeneration of the absorbent solution.Considering the regeneration energy consumption of the desorption system,working fluid circulation volume,and desorption efficiency,injecting a 15% rich solvent ratio at the 12th stage position is deemed appropriate. The payback period for the heat recovery process usingthe heat pump is 0.82 years,demonstrating significant economic value.

Keywords:
CO2 capture
MDEA-PZ absorbent
organic amine absorption method
Aspen plus
compression heat pump
renewable energy consumption
Citation format:
俞苗(1972—),男,浙江宁波人,高级工程师。E-mail:yu.miao@xizice.com
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Citation format:
YU Miao,XU Yanjie,FANG Mengxiang,et al. Compression heat pump in CO2-MDEA/PZ system for post combustion carbon dioxide capture[J].Clean Coal Technology,2024,30(10):70−77.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

  • Publication Frequencies

    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

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  • RCCSE(A+)
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