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Hydro-upgrading of crude algal bio-oil:Influence of external hydrogen sources

2024 No. 03
308
112
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Authors:
WANG Zhicong
XIE Longfei
DUAN Peigao
Unit:
School of Chemical Engineering and Technology,Xi′an Jiaotong University
Ecostar (Qingdao) Renewable Resources Co.,Ltd.
Abstract:

Catalytic hydrogenation is an effective way to improve the quality of crude algal bio-oil, in which hydrogen source is the keyfactor. The hydrogen production of five kinds of conventional metals (iron, aluminum, tin, zinc, magnesium) under supercritical waterwas investigated, and the hydrogen production of aluminum was the largest under the same mass. Then, using Ru/ C as catalyst, the upgrading effect of four different hydrogen sources(hydrogen produced from hydrothermal gasification of microalgae hydrothermal liquefactionaqueous phase-M-HTL-H2, hydrogen produced from hydrothermal gasification of Chlorella M-SCW-H2, hydrogen produced from the reaction of Al and high temperature water - Al - H2, and laboratory elemental hydrogen - L - H2 ) on microalgae crude bio - oil in tetrahydronaphthalene medium was studied at 400 ℃ and 2 h. The results show that, regardless of the hydrogen source, the upgraded bio-oilyield of the refined products is the highest, and the upgraded oil yield from L-H2 is the highest (87.6%), while the upgraded bio-oilyield from M-SCW-H2 is the lowest (70.4%). The four hydrogen sources also show different hydrogenation improvement effects on crudebio-oil, among which the deoxidation effect of Al-H2 on bio-oil is the highest (93.03%), and the calorific value of upgraded bio-oil isalso the highest (43.05 MJ/ kg). The nitrogen removal effect of M-SCW-H2 is the best (86.11%). The desulfuration effect of the four hydrogen sources on bio-oil is more than 90%. The hydrogen source also has a great influence on the composition of the upgraded bio-oil.The content of aromatic hydrocarbon and unsaturated hydrocarbon in the upgraded bio-oil obtained from L-H2 is the highest. The contentof saturated hydrocarbon is the highest and the content of aromatic hydrocarbon is the lowest in the upgraded bio-oil obtained from MHTL-H2. The results show that hydrorefining of crude bio-oil with different external hydrogenation sources can obtain different bio-oilquality improvement effects, and if these different hydrogen sources are combined, a better improvement in bio-oil quality can be obtained.

Keywords:
microalgae
crude bio-oil
hydro-upgrading
hydrogen source
Citation format:
王智聪(1997—),女,黑龙江哈尔滨人,博士研究生。E-mail:wzc2019@xjtu.stu.edu.cn
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Citation format:
WANG Zhicong,XIE Longfei,DUAN Peigao. Hydro - upgrading of crude algal bio - oil: Influence of external hydrogensources[J].Clean Coal Technology,2024,30(3):21-28.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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