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Research progress in catalytic conversion of biomass-based compoundsinto aromatic polycarboxylic acids

2024 No. 01
373
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Authors:
HU Yancheng
ZHANG Wenjing
CAO Jingpei
Unit:
School of Chemical Engineering and Technology,China University of Mining and Technology
Abstract:

Aromatic polycarboxylic acids, such as terephthalic acid, phthalic acid, trimellitic acid, trimesic acid and pyromellitic acid,are important bulk chemicals in modern industry. They can be used to prepare diverse polymers that have been widely applied in variousaspects of our daily life. Industrially, these compounds are obtained by catalytic oxidation of petroleum-derived aromatic hydrocarbons atelevated temperature and pressure. In the context of dual carbon strategy, using renewable biomass to replace traditional fossil energy toproduce chemicals is of great significance. The process for biomass conversion included catalytic degradation of biomass into a series ofC1-C6 platform molecules, and subsequent carbon-carbon couplings of these compounds. This review carefully summarized the advancesin catalytic conversion of biomass-based compounds into aromatic polycarboxylic acids. The novelty of these works is the establishment ofnew biomass-based synthetic process towards aromatic polycarboxylic acids, and the key challenging step is the construction of aromaticrings. To address this issue, two strategies have been developed: ① Diels-Alder reaction of furans with olefins and subsequent aromatization via dehydration. ② Alcohol dehydration to dienes and subsequent Diels-Alder reaction, followed by aromatization via dehydrogenation. This review is categorized by the types of aromatic polycarboxylic acids, including terephthalic acid, phthalic anhydride/ acid,benzenetricarboxylic acid, and pyromellitic acid. This review provides important guidance for the development of new biomass conversionsystem and process optimization.

Keywords:
aromatic polycarboxylic acid
biomass
catalytic conversion
platform molecules
Diels-Alder reaction
dehydration reaction
Citation format:
呼延成(1989—),男,江苏淮安人,教授,博士。E-mail:ychu@cumt.edu.cn
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Citation format:
HU Yancheng,ZHANG Wenjing,CAO Jingpei.Research progress in catalytic conversion of biomass-based compounds intoaromatic polycarboxylic acids[J].Clean Coal Technology,2024,30(1):87-100.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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