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Migration pattern and solidification treatment technology of heavymetals in coal gasification slag:A review

2023 No. 07
553
240
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Authors:
CHEN Bowen
XIONG Zhuo
ZHAO Yongchun
ZHANG Junying
Unit:
School of Energy and Power Engineering,Huazhong University of Science and Technology
State Key Laboratory ofCoal Combustion,Huazhang University of Science and Technology
National Environmental Protection EngineeringTechnology Center for Trace Elements Pollution Control and Low Carbon Utilization of Coal
Abstract:

With the continuous development of the coal gasification industry in China, the total amount of coal gasification slag is also in⁃creasing, and has become one of the urgent problem. In order to make full use of gasification slag, broaden its application scenario and re⁃flect the potential resource value, a lot of exploration has been carried out in the industries of construction materials, ceramics, molecularsieves, catalysts, etc., and it has been successfully used. However, during the coal gasification process, harmful heavy metal elements(Hg, Cr, Cd, Pb, Zn, Ni) in coal will remain in the gasification slag, which may be released or leached into the environment with pre⁃cipitation, causing adverse effects on the ecological living environment and human life and health, and affecting the comprehensive utiliza⁃tion of coal gasification slag. In the process of gasification, the release of heavy metals in coal is affected by the gasificationtemperature, mode and atmosphere, and different kinds of heavy metals are affected by these conditions in different ways and to differentdegrees. For heavy metals in gasification slag, the leaching rate is influenced by leachate pH, leaching temperature, solid-liquid ratio,particle size and leaching time, among which leachate pH is the main influencing factor. In order to stabilize the heavy metals in slag, re⁃duce the release and leaching of heavy metals and reduce the pollution to the environment, the sequestration treatment technology of heavymetals in coal gasification ash slag is systematically summarized and classified into six ways, such as cement sequestration, heat treatmentsequestration, hydrothermal treatment sequestration, additive sequestration, chemical co-precipitation sequestration and co-consolidationof mineralization according to the sequestration method.

Keywords:
coal gasifiation slag
heavy metals
migration and transformation
leaching behavior
solidification treatment
Citation format:
陈博文(1992—),男,河北邯郸人,博士研究生。E-mail:bwchen6080@163.com
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Citation format:
CHEN Bowen,XIONG Zhuo,ZHAO Yongchun,et al.Migration pattern and solidification treatment technology of heavy metals in coal gasification slag:A review[J].Clean Coal Technology,2023,29(7):173-188.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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    11-3676/TD

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