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Effect of acid-leached modification on the structure of USY zeolite and catalytic pyrolysis performance of coal

2023 No. 05
455
261
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Authors:
WU Zhuozhuo
YANG Zhiyuan
JU Xiaoqian
LI Yinyan
DUAN Xinbo
ZHOU Anning
Unit:
College of Chemistry and Chemical Engineering,Xi′an University of Science and Technology;Key Laboratory of Coal Resources Exploration and Comprehensive Utilization,Ministry of Natural Resources
Abstract:

Light aromatics (such as benzene, toluene, xylene, etc.) obtained from coal pyrolysis have significance for clean and efficient production of coal chemical industry. Based on commercial USY zeolite as the parent, this work investigates the types of acid, acid concentration on the influence of USY zeolite structure and coal catalytic pyrolysis performance. The texture and morphology of the modified zeolites were characterized by X-ray diffraction, scanning electron microscopy and N2 adsorption-desorption, and the effect of acid treatment on the pore structure of USY zeolite was studied. The catalytic cracking effect of the modified USY zeolite catalysts on the Shenfu coal was studied by Py-GC/MS. The results show that the crystallinity of USY zeolites decreases gradually with the increase of acid concentration. Under the condition of maintaining the skeleton integrity of the USY zeolites, the biggest impregnated HCl concentration is 0.4 mol/L, H2SO4 and H3PO4 is 0.2 mol/L. HCl modification can improve the average pore diameter and mesoporous volume of USY zeolite. The acid-leached USY zeolites 

are favorable for the formation of light aromatics, especially naphthalenes, in coal pyrolysis. HCl-USY-0.4 has the best catalytic effect, and the relative contents of benzenes, toluene, xylene and naphthalenes are 11.39%, 9.36%, 11.68% and 31.27%, respectively.

Keywords:
USY zeolites
acid-leached
coal
catalytic pyrolysis
light aromatics
Citation format:
吴卓卓(1998—),女,陕西渭南人,硕士研究生。E-mail:3229189827@qq.com
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Citation format:
WU Zhuozhuo,YANG Zhiyuan,JU Xiaoqian,et al.Effect of acid-leached modification on the structure of USY zeolite and catalytic pyrolysis performance of coal[J].Clean Coal Technology,2023,29(5):21-27.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    Coal Science Research Institute Co., Ltd
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    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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