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Research progress and prospects of mild oxidative depolymerization of low-rank coals

2022 No. 09
418
322
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Authors:
CHEN Jie
WANG Yugao
WANG Zhilei
SHEN Jun
NIU Yanxia
LIU Gang
SHENG Qingtao
Unit:
College of Chemical Engineering and Technology,Taiyuan University of Technology
Abstract:

 The implementation of "carbon peak and carbon neutral" policies will greatly limit the fuel-use of coals.  The low-rank coal is abundant in China, and it is not only inefficient to use it directly as energy, but also causes greater pollution. It is expected to develop a new process for production of carboxylic acid chemicals as well as expand the utilization of coal resources through the preparation of carboxylic acid chemicals by mild oxidative depolymerization of low rank coal. According to the difference of the methods, mild oxidative depolymerization of low-rank coals can be classified into non-catalytic oxidation (including chemical reagent oxidation and pretreatment oxidation), catalytic oxidation and in-situ oxidation. The development and characteristics of different oxidation methods for producing carboxylic acid chemicals from low-rank coals were mainly summarized. In non-catalytic oxidation, chemical reagent oxidation is easy to be carried out. Whereas it will cost a large consumption of chemical agents and the oxidation process is not easy to be controlled. At the same time, heteroatoms will be introduced into the resulting products for some oxidizing reagents such as nitric acid and sodium hypochlorite resulting in increasing difficulties of product separation. Pretreatment oxidation can improve the yield of products and utilization rate of low-rank coals, while the pretreatment process is relatively complicated. Catalytic oxidation method can speed up the reaction rate, and reduce investment and energy consumption. The stability, selectivity and efficiency of the catalyst need to be further studied, and the catalyst recovery should also be paid more attention. In-situ oxidation is flexible and controllable, which is expected to regulate the oxygen depolymerization process of low-rank coals. In the end, the current problems and future development direction of mild oxidative depolymerization of low-rank coals were discussed.

Keywords:
low-rank coals
mild oxidative depolymerization
carboxylic acid chemicals
chemical reaction
Citation format:
陈杰(1996—),男,山西临汾人,硕士研究生。E-mail:chenjie0601@link.tyut.edu.cn
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  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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