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New progress on sulfur resistance of VOCs combustion catalysts

2022 No. 02
581
259
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Authors:
WU Dongxia
CHENG Hang
HU Jiangliang
HOU Jiancai
CHANG Liping
WANG Jiancheng
BAO Weiren
Unit:
Key Laboratory of Coal Science and Technology,Ministry of Education and Shanxi Province,Taiyuan University of Technology;State Key Laboratory of Clean and Efficient Coal Utilization,Taiyuan University of Technology
Abstract:

Volatile organic compounds (VOCs) are important precursor of fine particulate matter(PM2.5) and O3 compound pollutants. VOCs pollution control has been listed as one of the important tasks in Chinese "13th Five Year Plan" environmental protection management. The “14th Five Year Plan” further pointed out that it is necessary to strengthen the management of urban air quality,promote the collaborative control of PM2.5 and O3,and accelerate the comprehensive treatment of volatile organic compounds emissions. Among various VOCs treatment technologies,catalytic combustion is the most effective method for VOCs treatment because of its wide range in the treatment concentration and no secondary pollution. However,there are usually a certain amount of sulfur compounds in the organic waste gas from coal chemical industry,coking plants,petroleum refineries and other industrial sources in the practical application process,which can interact with the catalyst to cause sulfur poisoning of the catalyst. Therefore,it is of great significance to control and design the catalyst and improve the sulfur tolerance of the catalyst for the treatment of VOCs. By analyzing the mechanism about the catalytic combustion of VOCs the important role of active oxygen in the process of catalytic combustion of VOCs was pointed out. The mechanism about sulfur poisoning of the catalyst was analyzed. The main causes about sulfur poisoning of the catalyst were given. According to the combustion mechanism and sulfur poisoning mechanism of the catalyst,four ways to improve the sulfur tolerance of the catalyst were summarized. Meanwhile,the characterization techniques of sulfur tolerance catalyst were given. On the basis of the global research status and technical level,the difficulties in the synthesis of sulfur tolerant catalysts and the future research focus were pointed out. There are three reaction mechanisms for the catalytic combustion of VOCs. The type of active oxygen is related to the reaction mechanism,and the type and concentration of active oxygen are closely related to the sulfur resistance of the catalyst. Therefore,it is of great significance to determine the catalytic reaction mechanism,analyze the type of active oxygen species and improve the oxygen reduction ability of the catalyst for the sulfur resistance of the catalyst. According to the sulfur poisoning mechanism of the catalyst,sulfides competed with VOCs to occupy the adsorption active sites,the active sites are reduced,and the catalyst is inactivated; sulfur compounds react with catalyst components to form sulfate,which blocks catalyst channels and covers catalyst active sites,resulting in sulfur poisoning of the catalyst. By introducing promoters,the acid and alkalinity of the catalyst can be adjusted,and the weak acidity of the catalyst can weaken the adsorption of sulfide. By introducing promoters and adding sulfating supports,the interaction between active components and sulfide can be weakened,and the acidification of active components can be weakened. The coexistence of water and sulfide in the catalytic combustion system can prevent the deposition of sulfate radical on the catalyst surface. The wet sulfate catalyst containing a large number of surface hydroxyl groups has higher surface acidity,thus promoting catalytic activity. The sulfur resistance of the catalyst can be improved by improving the oxidation-reduction performance of catalyst,inhibiting the adsorption of sulfide,weakening the interaction between sulfide and catalysts and controlling the composition of raw gas.

Keywords:
Volatile organic compounds(VOCs)
catalytic combustion
the mechanism of sulfur poisoning
sulfur tolerance
characterization techniques
Citation format:
吴冬霞(1995—),女,河北邯郸人,博士研究生。E-mail:DongxiaWu@yeah.net。通讯作者:胡江亮(1984—),男,河南郑州人,讲师,博士。E-mail:hujiangliang@tyut.edu.cn
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  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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