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Characteristics and influencing factors of coal-water slurry pyrolysis

2021 No. 05
513
373
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Authors:
FENG Fan
YU Juan
ZHANG Yao
LI Boyang
LIN Chen
ZHANG Zhongxiao
Unit:
School of Mechanical Engineering,Shanghai Jiao Tong University
Abstract:

The distribution,composition and yield of pyrolysis products of coal water slurry have an important influence on the effective combustion of coal-water slurry,while H2,CH4,CO and other gases produced by pyrolysis of coal-water slurry are conducive to improve the denitration temperature window and the denitration efficiency. In this paper,the coal-water slurry made from Shenmu coal(bituminous coal)was pyrolyzed by a high-frequency heating furnace,and the yield and composition of pyrolysis gas were measured and analyzed. The effects of pyrolysis temperature and heating rate on the pyrolysis characteristics of coal-water slurry were explored. The results show that as the temperature increases,the weight loss rate without water of coal-water slurry continues to increase,increasing by about 10% from 700 ℃ to 1 200 ℃. The yield of volatile matter and pyrolysis gas continue to increase,from 0.50 L/g to 0.73 L/g,which shows that the degree of pyrolysis of coal-water slurry gradually increases. The pyrolysis gas is mainly composed of H2,CO,CH4 and CO2. As the temperature rises,the total volume concentration of H2,CH4,CO2 and CO in the total pyrolysis gas decreases in the range of 700-900 ℃,and remains stable in the range of 900-1 100 ℃,and then continues to decline above 1 100 ℃,from initially 90% at 700 ℃ to 78% at 1 200 ℃,in which the volume concentration of H2,CO2 and CH4 decrease in a stepwise manner,while the volume concentration of CO remains almost unchanged. The volume concentration of H2 decreases most significantly,about 6.1%,while CH4 decreases by about 4% and CO2 decreases by about 2.6%. As the temperature increases,the yields of H2,CO2 and CH4 increase first and then decrease,and the peak appears at about 1 100 ℃,while the CO yield continues to increase. The yield of volatiles is affected by the rate of temperature increase. The weight loss rate without water at 667 ℃/min is 6% higher than that at 400 ℃/min. On the whole,the heating rate has not significantly influence on the pyrolysis. The research results provide a reference for understanding the formation characteristics of primary pyrolysis products of coal water slurry.

Keywords:
coal-water slurry
high-frequency heating furnace
pyrolysis
volatiles
heating rate
Citation format:
冯帆(1995—),男,北京人,硕士研究生,研究方向为NOx超低排放。E-mail:tony670132174@sjtu.edu.cn。通讯作者:于娟,副教授,研究方向为NOx超低排放、CO2捕集与利用。E-mail:yujuan@sjtu.edu.cn
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  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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