Chinese Science Citation Database Core Library(CSCD)Source Journals
Chinese Core Journals
Chinese Core Science and Technology Journals
RCCSE China Authoritative Academic Journal(A+)
Dutch Digest and Citation Database (Scopus)

Study on the direct liquefaction behaviors of Xinjiang Naomaohu coal

2021 No. 04
685
477
OnlineView
Download
Authors:
SHAN Xiangen
SHU Geping
CAO Xueping
WANG Hongxue
GAO Shansong
Unit:
National Engineering Laboratory for Direct Coal Liquefaction,China Shenhua Coal to Liquid and Chemical Company
Shanghai Research Institute
Abstract:

In order to study the direct liquefaction characteristics and product distribution of Naomaohu coal in Xinjiang,the effects of reaction temperature and reaction time on the yield of liquefied products were investigated in the 0.5 L batch autoclave with tetrahydronaphthalene as solvent,nano-iron oxide as catalyst and S as a promoter. The results show that Naomaohu coal is easy to be liquefied. When the reaction temperature just rises to 425 ℃,the conversion is up to 96.6%,and the oil yield is 56.68%. With the increase of reaction temperature and reaction time,coal conversion,hydrogen consumption,gas yield,and oil yield gradually increase,while the yield of asphaltic substances decreases and the water yield remains basically unchanged. Then,as the reaction temperature increases further and the reaction time continues to extend,the light oil will be further cracked,leading to further increase in gas yield and decrease in oil yield. When the reaction temperature is 455 ℃ and the reaction time is 80 min,the conversion rate of coal reaches 99.6%,the yields of oil,asphaltic substances,and gas are 73.42%,1.64%,and 16.61%,respectively,and the hydrogen consumption is 4.85%. According to the law of liquefaction reaction,five lumped reaction kinetic models were established. The Kinetic model parameters were obtained by using the optimization algorithm. The relative errors of the simulated and experimental values of coal conversion,asphalt substances,and oil and gas yield are 0.5%,1%,and 8%,respectively. 

Keywords:
direct coal liquefaction
bituminous coal
reaction properties
kinetic model
Citation format:
单贤根(1982—),男,江苏盐城人,高级工程师,博士,研究方向为煤直接液化。E-mail:xiangen.shan@chnerengy.com.cn
Chart:
Articles:
--
Citation format:
--

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

  • Publication Frequencies

    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

Covered by

  • CSTPCD
  • RCCSE(A+)
  • AJ
  • EBSCO host
  • Ulrichsweb
  • JST
  • Scopus

Contact us

New Media

  • Meichuanmei
    Meichuanmei
  • Clean Coal Technology
    Clean Coal Technology
  • Online Journals
    Online Journals
Website Copyright © {year} Clean Coal Technology
京ICP备05086979号-19
地址:Coal Tower, Hepingli, Chaoyang District, Beijing, China.
邮编:100013
Tel:86-10-87986452 / 010-87986451
E-mail:jjmjs@263.net