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Hydrocarbon resources production characteristics of in-situ pyrolysis ofShenfu tar-rich coal under mechanical-thermal coupling

2025 No. 02
102
54
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Authors:
GUO Wei
YU Zunyi
YANG Panxi
WANG Jing
YANG Fu
LI Hongqiang
GAO Kun
MA Li
JING Qingwen
YANG Bolun
WU Zhiqiang
Unit:
School of Chemical Engineering and Technology,Xi\'an Jiaotong University
Shanxi Key Laboratory of Energy ChemicalProcess Intensifcation
Shaanxi Provincial Coal Geology Group Co. Ltd.,Key Laboratory of Coal Resources Exploration andComprehensive Utilization,Ministry of Natural and Resources
School of Electrical Engineering,Xi’an Jiaotong University
Xi\'an Langjie Test Equipment Co.,Ltd
Abstract:

Given the challenges faced by in-situ pyrolysis of tar-rich coal,such as high ground stress,complex geological conditions,anddifficult analysis of pyrolysis products,a high-temperature triaxial test device was designed and built independently to simulate the in-situpyrolysis process of tar-rich coal. The test device includes a high-temperature and high-pressure gas supply module,an in-situ pyrolysismodule,a servo control module,and a product separation and cooling module. Taking the Shenfu tar-rich coal in Northern Shaanxi Province as the research object,the pyrolysis experiments of high temperature and high stress under different burial depths were simulatedbased on the high-temperature triaxial test device. The results show that the high-temperature triaxial apparatus can provide axialcompression of 0~15 MPa (buried depth of 0~600 m). The loading response is rapid,and the stress can remain stable duringpyrolysis. During the experiment,the high-temperature triaxial apparatus can heat the central temperature of coal samples over 600 ℃,and can realize the pyrolysis experiment of tar-rich coal at the set temperature. When the simulated burial depth increased from 100 m to300 m,the axial stress on coal samples increased from 2.45 MPa to 7.35 MPa,the yield of pyrolysis semi-coke risen from 67.70% to68.04%,and the tar yield first increased and then decreased,with the highest value of 6.50%. With the increase of simulated burial depth,the contents of light oil and phenol oil in tar gradually increased from 19% and 9.5% to 25% and 12% respectively. The proportion of pitchin tar is reduced from 25% to 20%; The aromatic hydrocarbon content increased from 32% to 38%,and the aliphatic hydrocarbon contentdecreased from 28.5% to 19.3%. The permeability of coal seam decreases with the increase of stress,which hinders the heat and masstransfer in the pyrolysis process,leading to the increase of residence time of pyrolysis products of tar-rich coal,the secondary reaction oftar,the fracture of long-chain aliphatic hydrocarbon compounds and the transformation of methyl and methylene into small molecularcompounds. On the other hand,stress promotes the condensation reaction of tar molecules and the content of polycyclic aromatichydrocarbons increases rapidly. The increase of in-situ stress improves the yield of light aromatics and coke,and the quality of tar isimproved to light weight.

Keywords:
Tar-rich coal
underground in-situ pyrolysis
high temperature triaxial apparatus
lightening tar
Citation format:
郭伟(1997—),男,安徽亳州人,博士研究生。E-mail:guowei131916@stu.xjtu.edu.cn
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Citation format:
GUO Wei,YU Zunyi,YANG Panxi,et al. Hydrocarbon resources production characteristics of in-situ pyrolysis of Shenfutar-rich coal under mechanical-thermal coupling[J].Clean Coal Technology,2025,31(2):67−75.

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    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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