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Effects of reaction temperature and pressure on the distributionof lignite pyrolysis products in Santanghu Basin

2024 No. 06
488
138
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Authors:
WANG Xinggang
JIAO Lixin
CAO Zhixiong
LI Bin
HAN Bo
HUANG Diefang
FU Yonghong
LI Xin
Unit:
Exploration and Development Research Institution,China Petroleum Tuha Oilfield Branch
Institute of Geology,China PetroleumLogging Co.,Ltd.
College of Geology and Mining Engineering,Xinjiang University
Abstract:

The gasification reaction efficiency of coal in the gasification channel is a key issue affecting the gas composition and calorificvalue of underground coal gasification. To reveal the effects of reaction temperature and pressure on the gasification behavior and productdistribution characteristics of lignite in water vapor using the coal deposited in the Santanghu Basin, pyrolysis experiments were carried outusing lignite collected from the Xishanyao Formation of the Santanghu Basin based on a fixed-bed pyrolysis furnace under different reactiontemperatures and pressures. With the increase of reaction temperature (300-900 ℃ ), the gas mass fraction increased from 3.84% to24.29%, and the mass fractions of water and tar increased first and then decreased. The volume of H2 and CH4 increased significantly withthe increase of reaction temperature, with the maximum volume of 100.89 and 106.09 mL/ g at 900 ℃ , respectively. The total mass of pollutants decreases, and the mass is relatively small at 900 ℃ , 17.72 mg/ g. Increasing the reaction pressure (1.5-3.0 MPa) is beneficialto improve the conversion of semi-coke and increase the gas mass fraction. The increase of reaction pressure aggravates the secondary reaction, which is conducive to the occurrence of hydrogasification reaction and methanation reaction, resulting in a significant increase in thevolume of CH4. At 700 ℃ , the volume of CH4 increases by up to 26.89 mL/ g. However at 700 ℃ , the free radical hydrogenation saturation reaction is promoted, resulting in an increase in the total mass of pollutants. It is suggested that in the actual production, the reactiontemperature and pressure should be increased by controlling the moving speed of steam injection, and the temperature of gasification reaction zone should be controlled away from 700 ℃ ,which is beneficial to the formation of H2 and CH4, so as to improve the efficiencyand clean development of underground coal gasification process. The research results can provide guidance for the underground coal gasification process of lignite in Xishanyao Formation of the Santanghu Basin.

Keywords:
Santanghu basin
coal pyrolysis
water vapor atmosphere
reaction temperature
reaction pressure
Citation format:
王兴刚(1983—),男,甘肃古浪人,高级工程师,硕士。E-mail:wangxinggangth@petrochina.com
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Citation format:
WANG Xinggang,JIAO Lixin,CAO Zhixiong,et al.Effects of reaction temperature and pressure on the distribution of lignitepyrolysis products in Santanghu Basin[J].Clean Coal Technology,2024,30(6):114-127.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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