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Kinetics and characteristics of light oil and heavy oil crackingin the micro-fluidized bed reactor

2024 No. 06
425
101
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Authors:
LI Dongsheng
LU Zhishuai
GUO Yue
LYU Zhongbin
ZHANG Hong
ZHANG Yuhui
JIA Xin
XU Guangwen
Unit:
Institute of Energy and Chemical Industry Technology,Shenyang University of Chemical Technology
Abstract:

The kinetics of tar cracking is essential to an accurate pyrolysis model and reactor design. Previous studies have predominantlyfocused on the overall cracking behavior of tar. However, it is evident that the cracking behavior differs significantly between light andheavy tar fractions. In order to gain a more precise understanding of the cracking behavior at different temperatures and establish a secondary reaction model, the cracking behavior and reaction kinetics of two distinct tar fractions were investigated using a micro fluidized bed reaction analyzer (MFBRA) under Ar atmosphere conditions at 550,600,650,700 ℃ . The results demonstrate that higher temperatures result in increased yields of cracking-formed gases. Specifically, light tar cracking primarily produces CO and CH4, while heavy tar generates CO, CH4, and H2 as its main products. Moreover, heavy tar exhibits more readily occurring cracking with shorter reaction times compared to light tar. By employing an isothermal method in MFBRA analysis, it is found that the average activation energy for light oil cracking was 49.49 kJ/ mol, which is higher than that for heavy oil cracking (33.47 kJ/ mol). Furthermore, by comparing activation energiesobtained from isothermal methods with mechanism models, suitable mechanism functions are identified: a chemical reaction (n= 2) modelfor CO during heavy oil cracking, three-dimensional diffusion models (spherical symmetry) for CH4 during both types of oil cracking, anda contraction geometry model (cylindrical symmetry) for H2 specifically during heavy oil cracking but not present in light oil cracking scenarios. These results provide valuable insights into developing reasonable secondary reaction models for simulating selective oil cracking.

Keywords:
tar cracking
kinetics
micro fluidized bed
heavy tar
light tar
activation energy
mechanism function
Citation format:
李东升(1998—),男,辽宁朝阳人,硕士研究生。E-mail:980777970@qq.com
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Citation format:
LI Dongsheng,LU Zhishuai,GUO Yue,et al.Kinetics and characteristics of light oil and heavy oil cracking in the micro-fluidized bed reactor[J].Clean Coal Technology,2024,30(6):95-104.

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  • Executive director

    China Coal Science and Industry Group Co., Ltd

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    Technology Research Center

  • Editor in Chief

    XIE Qiang

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    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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