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Development progress of chemical absorbents for carbon dioxide chemicalabsorption from flue gas of coal-fired power plants

2024 No. 11
342
129
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Authors:
HE Xuefeng
FAN Hao
SHEN Zhenxing
CHANG Tian
PENG Qin
SONG Bo
Unit:
School of Energy and Power Engineering,Xi’an Jiaotong University
School of Environmental Science and Engineering,Shaanxi University of Science and Technology
Abstract:

According to the sequence of research and development of chemical absorbers,the technical characteristics and performancedifferences of single amine absorbers, mixed amine absorbers, biphasic absorbers, non-aqueous absorbers and ionic liquids aresummarized,and the progress of post-combustion chemical absorption capture technology is introduced with specific cases. To addressthe problem of high energy consumption in the regeneration of traditional single amine absorbers,solid acid catalysts,some amino acidsand derivatives or some metal ions are often used to assist the regeneration process to reduce energy consumption. Mixed amineabsorbents combine different ratios of primary, secondary, tertiary or site-resistant amines with different advantages to enhance theperformance. Biphasic absorbents reduce regeneration energy by regenerating only the rich liquid phase after absorption. In industrialapplications, 2-amino-2-methyl-1-propanol (AMP) is commonly used to reduce viscosity, and polyethylene glycol dimethyl ether(NHD) or sulfoxide is used to promote phase separation. Non-aqueous absorbers use physical solvents instead of traditional water toreduce the water content and thus the regeneration energy consumption. Commonly used physical solvents are mainly alcohols and theirderivatives. In addition,functionalized ionic liquids with better CO2 absorption performance are made by introducing primary aminegroups into conventional ionic liquids. Ethylene glycol (EG),n-propanol,Monoethanolamine (MEA),N-methyl diethanolamine(MDEA),etc. and some functional ionic liquids can reduce viscosity and regeneration heat. However,the current absorbers also haveproblems such as high energy consumption,easy degradation and escape of absorber amine. There is an urgent need to develop chemicalabsorbents with low energy consumption,low loss,low cost and good absorption performance to realize the large-scale application of fluegas CO2 capture technology. 

Keywords:
CO2 capture
chemical absorption
chemical absorbents
regeneration energy consumption
viscosity
industrial applications
Citation format:
贺雪峰(2000—),男,陕西西安人,硕士研究生。E-mail:hexuefeng2023@163.com
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Citation format:
HE Xuefeng,FAN Hao,SHEN Zhenxing,et al. Development progress of chemical absorbents for carbon dioxide chemical absorption from flue gas of coal-fired power plants[J].Clean Coal Technology,2024,30(11):82−96.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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