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Chemical extraction and precipitation recovery performance of phosphorus fromfour kinds of sludge heat treatment products

2024 No. 03
229
84
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Authors:
ZHANG Zhihan
LUO Xinyi
ZHANG Aijia
YANG Yingju
LIU Jing
QIAO Yu
Unit:
State Key Laboratory of Coal Combustion,School of Energy and Power Engineering,Huazhong University of Science and Technology
Abstract:

Sewage sludge contains a large amount of phosphorus, and the recovery of phosphorus can realize the secondary utilization ofphosphorus resources. The phosphorus recovery experiments in the acid leaching solution of four kinds of sludge thermal treatment products, including smoldering ash, mixed ash, incineration ash and pyrolysis coke were conducted by the magnesium ammonium phosphate(MAP) recovery method. The phosphorus recovery performance of each thermal treatment product under the acid leaching-MAP recoveryprocess route was analyzed. The phosphorus precipitation rate, the phosphorus and impurities contents in the products were explored. Theenvironmental safety of the precipitated products was further investigated. The results show that the phosphorus content of the precipitateproduct can reach 19.82-31.71 mg/ g, and the phosphorus recovery rate in the original sludge reaches 49.25%-65.81% by the acid leaching-MAP recovery method. The order of the phosphorus recovery performance is incineration ash > pyrolysis coke > smoldering ash >mixed ash. There are a large number of Ca, Fe, Al and Si impurities in the acid leaching MAP recovery product, and a certain amount ofZn, Pb, Cr, Cu, Cd, As and Ni, with Zn content much higher than other heavy metals. The purity and environmental safety of the products follows the order of incineration ash > mixed ash > pyrolysis coke > smoldering ash. In the terms of the environmental safety of theprecipitated products, the heavy metal content of the acid leaching-MAP recovered products of smoldering ash, incineration ash and pyrolysis coke all meet the " Ecological Index of Arsenic, cadmium, lead and mercury in Fertilizers" written in GB/ T 23349—2009 and the" Control Standard of Pollutants in Agricultural Sludge" written in GB 4284—2018. The content of Cd in the recovered product fromthe mixed ash using acid leaching-MAP is 3.20 mg/ kg, which exceeds the limited value of 3.00 mg/ kg for pollutant control of agriculturalsludge.

Keywords:
sludge
thermal treatment
phosphorus recovery
acid leaching - magnesium ammonium phosphate
phosphorus precipitationrate
impurity content
Citation format:
张芷晗(2003—),女,辽宁铁岭人。E-mail:u202111406@hust.edu.cn
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Citation format:
ZHANG Zhihan,LUO Xinyi,ZHANG Aijia,et al.Chemical extraction and precipitation recovery performance of phosphorusfrom four kinds of sludge heat treatment products[J].Clean Coal Technology,2024,30(3):52-58.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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    1006-6772

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    11-3676/TD

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