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Advancements in CO2 adsorption performance of porous organic frameworkstructures and their derivatives

2025 No. 02
150
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Authors:
ZHANG Yuke
LI Xiangyu
WANG Jiancheng
YI Qun
Unit:
State Key Laboratory of Clean and Efficient Utilization of Coal-Based Energy,Taiyuan university and technology
College ofEnvironmental Science and Engineering,Taiyuan university and technology
School of Chemical Engineering andPharmaceutical Sciences,Wuhan Institute of technology
Abstract:

In response to the urgent need to address global climate change and reduce greenhouse gas emissions,the development ofefficient and cost-effective CO2 capture technologies has become a primary focus of scientific research. In this context,Metal-OrganicFrameworks (MOFs) and Covalent Organic Frameworks (COFs),along with their derivatives,have emerged as prominent areas ofstudy due to their unique physicochemical properties. This paper systematically reviews and analyzes recent advancements in CO2adsorption research related to MOFs,COFs,and other porous structures. It compares and explores the performance optimizationstrategies for CO2 capture in MOFs,COFs,and their derivatives. The focus is on aspects such as material design and synthesis,CO2adsorption performance evaluation,and adsorption mechanism analysis. The key factors influencing structural adsorption performancewere comprehensively summarized,with particular emphasis on the impact of structural functionalization,pore size modulation,surfaceproperty enhancement,and composite materials on CO2 adsorption capacity. Additionally,it discusses the combined experimental andtheoretical approaches used to reveal the interaction mechanisms between adsorbents and adsorbates,providing molecular-level insights.Finally,the paper addresses existing problems and challenges in current research and proposes directions and recommendations for futurestudies. 

Keywords:
carbon dioxide
adsorption
porous material
metal organic frameworks
covalent organic framework
Citation format:
张雨珂(1995—),女,山西晋城人,博士研究生。E-mail:zhangyuke0145@link.tyut.edu.cn
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Citation format:
ZHANG Yuke,LI Xiangyu,WANG Jiancheng,et al. Advancements in CO2 adsorption performance of porous organicframework structures and their derivatives[J].Clean Coal Technology,2025,31(2):178−191.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

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