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Preparation of porous glass-ceramics from coal gasification fine ash slag

2024 No. 07
503
123
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Authors:
ZHOU Li
REN Qiangqiang
CUI Ruifang
LI Linxuan
LI Wei
Unit:
State Key Laboratory of Coal Conversion,Institute of Engineering Thermalphysics,Chinese Academy of Sciences
University of Chinese Academy of Sciences
Abstract:

ous environmental pollution and resource waste. The treatment of coal gasification fine ash by fluidization melting can realize the separationof carbon and ash, and the modification and improvement of ash, so that ash can be transformed into glass phase slag rich in silicon andaluminum elements. Because of its special glassy interwoven structure, porous glass-ceramics have good mechanical properties and thermalinsulation properties, so the idea of high value utilization of molten slag to prepare porous glass-ceramics was established. The effects ofpre-curing time and sintering temperature on crystallization characteristics, pore structure and compressive strength of porous glass-ceramics were studied. The results show that the crystallization characteristics and pore structure of porous glass-ceramics are related to sintering temperature and pre-curing time. The higher sintering temperature can promote the crystal phase precipitation in the sinteringprocess and strengthen the compressive strength of the porous glass-ceramics. The pre-curing time affects the network structure of the porous-glass embryo, resulting in different resistance to be overcome during crystal precipitation, which affects the type of crystal phase.When the pre-curing time is 30 min, the large pore size of the porous-glass embryo is easy to collapse during the process of sinteringand crystallization. The compressive strength decreases with the increase of porosity and decreases nonlinearly with the increase of poresize. When the pre-curing time is 90 min, a good pore structure can be obtained. The compressive strength is influenced by the crystallization characteristics and the pore structure characteristics. When the sintering temperature is 900 ℃ , the compressive strength can bestrengthened, especially when the pre-curing time is 90 min, the compressive strength of the porous glass-ceramics is 3.77 MPa. At700 ℃ and 800 ℃ , whether the compressive strength increases is related to the pre-curing time. When the pre-curing time is 60 min andthe sintering temperature is 900 ℃ , a large number of crystals are precipitated, the porosity is 66.20%, the pore size is evenly distributed, and the compressive strength is 1.40 MPa.

Keywords:
slag
porous glass-ceramics
pre-curing time
sintering temperature
pore structure
compressive strength
Citation format:
周丽(1996—),女,甘肃平凉人,博士研究生。E-mail:zhouli@iet.cn
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Citation format:
ZHOU Li,REN Qiangqiang,CUI Ruifang,et al.Preparation of porous glass-ceramics from coal gasification fine ash slag[J].Clean Coal Technology,2024,30(7):69-77.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

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