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Review on characteristics and resource utilization of coal gasification coarse slag

2024 No. 07
790
317
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Authors:
ZHANG Kewei
LIAO Changjian
WANG Jing
JIN Ping
WANG Kun
XU Wanyi
Unit:
Chemical Institute of China Petrochemical Corporation
Dalian Research Institute of Petroleum and Petrochemicals
Abstract:

slag is large while the utilization rate is low. Coal gasification slag is usually disposed by storage and landfill, resulting in serious waste ofland resources and environmental pollution. The resource utilization of coal gasification slag has become the research emphasis ofcoal chemical industry, especially the coal gasification coarse slag, which accounts for 70%-80% of the total coal gasification slag. In thispaper, three coal gasification processes and the formation of coal gasification coarse slag were introduced, and the physicochemical characteristics and environmental risks of coal gasification coarse slag were summarized, and the research progress of coal gasification coarse slagin the utilization of building materials, soil improvement and high value utilization were sum up. Affected by the main control factors suchas coal type and coal gasification process, the physical and chemical characteristics and environmental risks of the gasification coarse slagfrom different sources are not the same, but they do have some commonalities. The particle size of coarse slag is much higher than that offine slag, about 50% of coarse slag has a particle size of more than 0.5 mm, and the content of coarse slag of different particle sizes lessthan 0.5 mm decreases with the decrease of particle size, and the coarse slag also has a smaller specific surface area and a larger averagepore size. The carbon residue content of coarse slag is lower than that of fine slag, and the carbon residue content of coarse slag is generally in the range of 3%-20%, which is unevenly distributed in different particle size grade. Generally, the medium particle size coarse slagof about 0.25 mm has a higher carbon residue content. The inorganic components in the slag are mainly SiO, AlO, CaO and FeO, ofwhich the acid oxides account for 45%-75%, while the basic oxides account for about 20%-45%. There is a certain enrichment of heavy metalsin the coarse slag, including some lithophilic elements such as Ba, Co, Cs, Th, and some non-volatile or semi-volatile elements such asCr and Ni. In addition, the acid extractable content of heavy metals such As Ni, Cd, As, Cu and Zn in coarse slag is high, whichhas great environmental risks and needs special attention. The physical and chemical characteristics of coarse slag and its environmentalrisks have a great impact on the applicable resource utilization. Coarse slag can be widely used in building materials such as mine backfill,road construction, cement and concrete, ceramide and wall materials due to its low carbon residue content and high inorganic component content such as silicon and aluminum. Coarse slag with higher carbon residue content has more loose and porous structure characteristics, which can be used for soil improvement. The special structure of coarse slag and its abundant silicon and aluminum components makethe coarse slag have great potential in preparing porous adsorption materials and ceramics. The coarse slag can also be used to prepare catalyst or extract and recycle alumina and other high value utilization. The coarse slag contains certain kinds of heavy metals, which has certain environmental risks and restricts the comprehensive utilization of the gasification slag. Therefore, before the resource utilizationof coarse slag, it is necessary to comprehensively analyze the enrichment and occurrence state of various heavy metals, and strictly controlthe environmental risk assessment, thus avoiding the secondary pollution caused by the resource utilization of coarse slag.

Keywords:
coal gasification coarse slag
physical and chemical characteristics
heavy metals
resource utilization
building materials
soil improvement
high value utilization
Citation format:
张可伟(1979—),男,河南洛阳人,高级工程师,硕士。E-mail:zhangkewei@sinopec.com
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Citation format:
ZHANG Kewei,LIAO Changjian,WANG Jing,et al.Review on characteristics and resource utilization of coal gasification coarse slag[J].Clean Coal Technology,2024,30(7):13-29.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

  • Publication Frequencies

    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

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  • CSTPCD
  • RCCSE(A+)
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