Chinese Science Citation Database Core Library(CSCD)Source Journals
Chinese Core Journals
Chinese Core Science and Technology Journals
RCCSE China Authoritative Academic Journal(A+)
Dutch Digest and Citation Database (Scopus)

Investigationon regulation mechanism of sludge on the ash melting characteristics ofcoal with high ash fusion temperature (AFT)

2023 No. 07
474
322
OnlineView
Download
Authors:
LI Meng
CHEN Xueli
LI Fenghai
XU Jianliang
LIU Xia
Unit:
Engineering Research Center of Resource Utilization of Carbon-containing Waste with Carbon Neutrality,Ministry of Education,East China University ofScience and Technology
School of Chemistry and Chemical Engineering,Heze University
Abstract:

The reserve of high ash fusion temperature coal in China is huge, and the content of silicon and aluminum in the ash is high,while the content of basic oxide in some sludge is high. The co-gasification of sludge and high ash fusion temperature coal provides thepossibility of regulating the ash melting characteristics of high ash fusion temperature coal. In this study, the effects of municipal sludge(CS) and pharmaceutical sludge (ZY) on the ash melting characteristics of Jiaozuo coal (JZ) with high ash fusion temperature wereinvestigated. The results show that adding CS ash and ZY ash to JZ ash can reduce ash fusion temperature of JZ and adding ZY ash hasa more significant effect on reducing the ash fusion temperature of JZ. When the CS and ZY ash ratio is 15% and 10%, respectively,the flow temperature of JZ-CS and JZ-ZY mixtures are reduced to below 1 380 ℃ to meet the slag discharge requirements of entrainedflow gasifier CS ash has a high CaO content, and ZY ash has a high Fe2O3 content. With the addition of CS ash, the amount of anorthiteformed by reaction of CaO in CS ash with Al2O3 and SiO2 increases,and its co-melting with quartz results in the increase of liquidphase content and the decrease of ash melting temperature. Under a weak reducing atmosphere, the Fe3+ in JZ-ZY ash is reduced intoFe2+, and iron-bearing minerals such as hercynite increases. Hercynite with low melting point can melt at low temperature, and ironbearing minerals easily form low melting point eutectic with other minerals, which decreases the ash fusion temperature (AFT) of JZ.When the proportion of sludge ash added is the same, compared with JZ-CS ash, JZ-ZY ash has a lower theoretical solid content, low⁃er intensity and quantity of crystal phase diffraction peaks. When the temperature is 1 500 ℃ , the mixed ash with 25% ZY ash reachesthe full liquid state, while the mixed ash with 25% CS ash still contains some mullite. Mole ionic potential α is positive linearly correla⁃ted with the characteristic temperatures of both types of mixed ash. The decrease in α value of JZ-ZY ash is greater, so the melting tem⁃perature of JZ-ZY ash decreases more significantly.

Keywords:
high ash fusion temperature coal
sludge
ash melting characteristic
flow temperature
regulation mechanism
Citation format:
李萌(1996—),山东菏泽人,博士研究生。E-mail:lm1723346206@163.com
Chart:
Articles:
--
Citation format:
LI Meng,CHEN Xueli,LI Fenghai,et al.Investigationon regulation mechanism of sludge on the ash melting characteristics of coal with high ash fusion temperature (AFT)[J].Clean Coal Technology,2023,29(7):198-208.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

  • Publication Frequencies

    Monthly

  • ISSN

    1006-6772

  • CN

    11-3676/TD

Covered by

  • CSTPCD
  • RCCSE(A+)
  • AJ
  • EBSCO host
  • Ulrichsweb
  • JST
  • Scopus

Contact us

New Media

  • Meichuanmei
    Meichuanmei
  • Clean Coal Technology
    Clean Coal Technology
  • Online Journals
    Online Journals
Website Copyright © {year} Clean Coal Technology
京ICP备05086979号-19
地址:Coal Tower, Hepingli, Chaoyang District, Beijing, China.
邮编:100013
Tel:86-10-87986452 / 010-87986451
E-mail:jjmjs@263.net