Medium and high temperature gas desulfurization is one of the key technologies to realize the clean and efficient utilization ofcoal. The mechanism of sulfide growth and diffusion in the kinetics of metal oxide desulfurization reaction indicates that keeping the activecomponent of desulfurization sorbent with high dispersion and small size is beneficial to reduce the diffusive and mass transfer resistanceof the desulfurization reaction and to improve the utilization of the active phase. A series of zinc-manganese composite oxidedesulfurization sorbent were hydrothermally synthesized using different types of zinc salts and hexamethylenetetetramine (HMTA) onnanofiber supporter loaded with MnO2 seed layer,and the nucleation and growth mechanisms of the active-phase crystals were elucidatedby exploring the interrelationships between the type of counter-ion and the grain size of zinc-manganese oxides. It was shown that thecounter-ion in hydrothermal solution have a significant inhibitory behavior for the complexation and condensation reaction of Zn withOH. Compared with NO3and SO4,the average grain size of Mn3O4 crystal phase in the desulfurization sorbent decreased by 39.2%,andthe particle size of the active phase decreased by 24.7%. Meanwhile,desulfurization tests showed that the overall active componentutilization of the desulfurization sorbent ZN@MCNFs was 7% higher than that of ZS@MCNFs. The crystal growth mechanism of zinc-manganese-based desulfurization sorbent elucidated by the research provides theoretical support for the development of metal oxidedesulfurization sorbent with excellent performance.

武帅山(1999—),男,山西朔州人,硕士研究生。E-mail:2192834200@qq.com

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WU Shuaishan,SUN Yangjie,NIU Fangfang,et al. Study of crystal growth mechanism in hydrothermal synthesis of zinc-manganese based desulfurization sorbent[J].Clean Coal Technology,2025,31(2):49−58.