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Advances in catalysts and project progress for CO2 hydrogenation to methanol

2024 No. 08
466
339
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Authors:
YE Zhiyuan
RAO Na
XIA Changyou
LIU Shuo
LIANG Xi
Unit:
Guangdong CCUS Centre
Institute of Energy Research,Jiangxi Academy of Sciences
Ningxia Electric Power Design Institute
University College London
Abstract:

Methanol is a crucial organic raw material and fuel,particularly in the context of the climate and energy crisis. Developinga methanol economy is crucial to promoting a green,low-carbon transformation of the chemical,energy,and transportation sectors while ensuring a secure energy supply. A comprehensive overview of the CO hydrogenation process routes to methanol was offered,including an analysis and summary of the performance of copper-based,indium-based,solid solution,and noble metal catalysts. The data show that thereaction conditions of all four types of catalysts are concentrated at 200-300 ℃ and 1.5-5.0 MPa. While copper-based catalysts werethe most widely studied and applied,with a median CO conversion and methanol selectivity of 13.6 and 69.2,respectively ,indium-based catalysts and solid solution catalystshavecomparable CO conversion and methanol selectivity but exhibit better stability. The extremevalues of CO conversion and methanol selectivity for noble metal catalysts vary significantly,with limited data related to stability. Solid solution catalysts demonstrate exceptional catalytic performance and stability under industrial conditions,making them a promising catalysttype for large-scale application in the future. Furthermore,this paper provides an overview of existing CO hydrogenation to methanol projects and technical routes both domestically and abroad. The number of carbon dioxide hydrogenation to methanol projects is increasing,with production capacities ranging from 4 000 t/ a to 200 000 t/ a. Industrial emission source CO capture devices as the carbon source andelectrolytic water as the primary source of hydrogen were primarily relied on. As the goal of carbon neutralization becomes increasingly critical,the CO hydrogenation to methanol technology becomes even more vital. Therefore,it is recommended that the research and development of CO hydrogenation to methanol catalyst technology receive greater support,as well as the industrial application of the project.

Keywords:
CCUS
methanol
carbon utilization
catalyst
CO2
Citation format:
叶知远(2000—),男,湖北监利人,职称,学历。E-mail:yezhiyuan@gdccus.org
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Citation format:
YE Zhiyuan,RAO Na,XIA Changyou,et al.Advances in catalysts and project progress for CO2 hydrogenation to methanol[J].Clean Coal Technology,2024,30(8):150-161.

About Journal

  • Executive director

    China Coal Science and Industry Group Co., Ltd

  • Sponsored by

    Coal Science Research Institute Co., Ltd
    Coal Industry Clean Coal Engineering
    Technology Research Center

  • Editor in Chief

    XIE Qiang

  • Vice Editor-in-Chief

    YU Chang
    SHI Yixiang
    ZHAO Yongchun
    DUAN Linbo
    CAO Jingpei
    ZENG Jie

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