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    煤气化渣资源化利用研究进展及应用展望

    Research progress and application prospect of coal gasification slag resource utilization

    • 摘要: 介绍了煤气化渣的主要来源、危害以及煤气化渣的理化特性,论述了不同煤气化工艺(包括固定床、流化床、气流床)产生的煤气化渣利用的研究现状,讨论了煤气化渣在锅炉掺烧、水泥和混凝土填料、制砖、吸附、工业材料及农业方面的利用现状,展望了煤气化渣的应用前景。目前煤气化渣利用率低,炭灰相互制约,锅炉掺烧和建工建材为主要利用途径,高值化利用大多处在实验室研究阶段。锅炉掺烧是就地解决煤气化渣的主要途径,煤气化渣水分高、残炭较低、热值不够,在实际应用中还应考虑经济效益和对锅炉系统的稳定性影响;建工建材是煤气化渣的规模化消纳路径,但煤气化渣烧失量较高已超过国家和行业标准,残炭属于惰性物质,会影响水泥和混凝土及砖材的质量;吸附在实际工程领域可能会存在水体二次污染、生产技术复杂和投资风险较高等问题,目前仍需结合生产实际进一步优化设计及试验;制备催化剂载体、橡塑填料、碳硅复合材料、聚合氯化铝絮凝剂、陶瓷材料等工业材料是目前研究热点,产品附加值高,但成本高,工艺复杂,大多处于实验室研究阶段,需开发具有可行性的工业路线,进一步拓展煤气化渣高值资源化利用方式,为其高值化利用提供技术支撑;煤气化渣用于沙土改良、堆肥添加剂、重金属降解等方面研究较多,但煤气化渣中的重金属对环境的风险仍需深入研究。为了提高企业经济效益,解决煤气化渣环保难题,针对煤气化渣堆放和填埋现状,基于煤气化渣产量大、碳铝硅资源丰富、比表面积大、孔隙结构发达的特性,建议煤气化渣分级利用,逐步开发工艺简单、可行性强且具有经济效益的煤气化渣灰炭分离利用等技术,适度开发煤气化渣在生态领域的应用,实现煤气化渣的无害化、减量化和资源化。

       

      Abstract: The research introduced the main sources and hazards of coal gasification slag and the physical and chemical properties of coal chemical gasification slag, and discussed status of slag generated by different coal gasification processes(including fixed bed, fluidized bed and entrained flow bed),further discussed the utilization status of coal gasification slag in boiler blending, cement and concrete filler, brick making, adsorption, industrial materials and agriculture and outlooks the application prospects of coal gasification slag. At present, the utilization rate of coal gasification slag is low, the carbon and ash are mutually restricted, boiler blending and the constmction materials are the main utilization way, and the high value utilization is mostly in the laboratory research stage. Boiler blending is the main way to solve the coal gasification slag locally, because of high moisture, low carbon residue and insufficient calorific value, so in practical application need to consider economic benefits and impact on the stability of boiler system.Construction materials is the scale of coal gasification slag elimination path, but the high burn loss of coal gasification slag has exceeded national and industry standards, the residual carbon is inert substance which affects the quality of cement and concrete and bricks.Adsorption in the field of actual engineering may exist water secondary pollution, production technology complexity and high investment risk which still need to be further optimized with the actual production design and test.The preparation of catalyst carrier, rubber and plastic filler, carbon and silicon composites, polyaluminium chloride, ceramic material and other industrial materials is the current research hotspots, with high value-added products, but the high cost and complex process, mostly in the laboratory research stage and need to develop feasible industrial routes to further expand the high-value resource utilization of coal gasification slag and provide technical support for its high-value utilization.The use of coal gasification slag for sand improvement, compost additive and heavy metal degradation has been flourishing, but the risk of heavy metals in coal gasification slag to the environment still needs in-depth research. In order to improve the economic efficiency of enterprises and solve the environmental problems of coal gasification slag, in view of the current situation of coal gasification slag piling and landfill, based on the characteristics of large production of coal gasification slag, abundant carbon aluminum silicon resources, large specific surface area and well-developed pore structure, it is suggested that coal gasification slag grade utilization, and gradually develop simple, feasible and economic benefits of the gasification slag ash separation and utilization technology, moderate development of gasification slag in the ecological field of application, to achieve the harmlessness, reduction and resource of coal gosification slag.

       

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