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    面向CO2捕集的煤沥青衍生多孔炭应用研究进展

    Research progress on the application of coal asphalt derived porous carbon for CO2 capture

    • 摘要: 随着全球气候问题日益严峻,碳捕集技术对于实现“双碳”目标的重要性愈加凸显。开发高效且低能耗的先进CO2固体吸附材料是碳捕集领域的研究焦点。煤沥青作为煤热转化的衍生物不仅含碳量高、成本低且产量大,且其衍生的多孔炭吸附剂具有优异的理化性能和结构稳定性,在CO2捕集方面展现出巨大潜力。综述了煤沥青基吸附剂的制备方法和碳捕集性能提升策略,为利用煤沥青开发低成本且性能优异的碳捕集吸附剂提供了重要参考和技术支撑。首先,介绍了煤沥青基吸附剂的吸附机理并详细阐述了其在碳捕集过程中的复合吸附机制,随后详尽讨论了基于模板法、活化法等方法制备煤沥青基多孔炭的特点与进展。在此基础上,进一步全面梳理了杂原子掺杂、金属掺杂改性和其他改性技术等策略在提升煤沥青基多孔炭性能方面的强化机制,讨论了性能提升方式对煤沥青基多孔炭的孔隙结构和CO2吸附性能的作用效果。最后,聚焦于煤沥青基多孔炭在碳捕集实际应用中亟待解决的瓶颈问题,结合不同工艺优化技术对其未来发展前景进行了展望。

       

      Abstract: With the increasingly severe global climate problem, the importance of carbon capture technology in achieving the“dual carbon”goal is becoming more prominent. The development of efficient and low-energy advanced CO2 solid adsorption materials is a research hotspot in carbon capture. Coal asphalt, as a derivative of coal thermal conversion, not only has high carbon content, low cost, and high yield, but also its derived porous carbon adsorbent has excellent physical and chemical properties and structural stability, showing great potential in CO2 capture. The article summarizes the preparation methods and carbon capture performance improvement strategies of coal asphalt-based adsorbents, providing important reference and technical support for the development of low-cost and high-performance carbon capture adsorbents using coal asphalt. Firstly, the adsorption mechanism of coal asphalt-based adsorbent is introduced and its composite adsorption mechanism in carbon capture process is elaborated. Then, the characteristics and progress of preparing coal asphalt-based porous carbon based on template method, activation method and other methods are discussed in detail. On this basis, the strengthening mechanisms of strategies such as heteroatom doping, metal doping modification, and other modification techniques in improving the capture performance of coal asphalt-based porous carbon are further comprehensively reviewed. The effects of current performance improvement methods on the pore structure and CO2 adsorption performance of coal tar pitch based porous carbon are discussed. Finally, focusing on the bottleneck problems that urgently need to be solved in the practical application of coal tar pitch based porous carbon in carbon capture, the future development prospects are discussed in combination with different process optimization technologies.

       

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