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    基于多物理场耦合仿真的碱性电解槽极板结构优化研究

    Optimization of bipolar plate structure in alkaline electrolyzer based on multi-physics simulation

    • 摘要: 碱性电解水技术是目前主流的可再生能源制氢方式,其中乳突状极板在碱性电解槽中得到广泛应用。本文采用数值模拟方法建立碱性电解槽多物理场仿真模型,基于仿真模型研究极板乳突间隔排列、交叉排列、顺次排列三种排列方式及其乳突间距离对电解槽多物理场分布及电解水制氢性能的影响,并提出优化策略。研究发现,乳突结构可显著改善极板的电解反应强度和气体组分分布,但这一结构也会带来气泡和温度积聚问题;工作电压为1.8 V、工作温度为70 ℃时,间隔为15 mm的交叉排列构型的极化电流密度可达2004 A/m2,最高温升相比其他构型可降低近2℃,在温度均匀性、气体体积分数与流场均匀性等方面均表现良好。

       

      Abstract: Alkaline water electrolysis (AWE) technology is currently a mainstream method for producing hydrogen from renewable energy sources, and spherical concave-convex (SCC) shaped bipolar plate are widely used in alkaline electrolyzers. In this paper, a multi-physical simulation model of alkaline electrolyzer is established using numerical simulation methods. Based on the simulation model, we propose to study the effects of three arrangements of SCC, namely, alternate arrangements, cross arrangements and sequential arrangements, and of the distance of SCC on the distribution of physical fields and hydrogen production performance, for proposing an optimization strategy. The study found that the SCC structure can significantly improve the electrolysis reaction strength and gas component distribution on the electrode, but this structure also brings problems of bubble formation and temperature accumulation. When the operating voltage is 1.8 V and the temperature is 70 ℃, the polarization current density of the cross arrangement of SCC with a spacing of 15 mm can be more than 2000 A/m2, the maximum temperature rise can be lowered by nearly 2 ℃ compared with other structures, and it has good performance in terms of temperature uniformity, gas fraction, and flow field uniformity.

       

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