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    废风电叶片回收玻璃纤维的改性与应用

    Modification and application of recycled glass fibers from waste wind turbine blades

    • 摘要: 随着风电装机规模持续增长及早期风电机组逐步进入退役期,废风电叶片产生量不断攀升。风电叶片主体为玻璃纤维增强树脂复合材料,具有难降解、难分离和一定的资源化价值等特点,提升其资源化价值已成为风电固废处理的重要研究方向。围绕废风电叶片中回收玻璃纤维(RGF)的高值化利用,阐述了不同回收工艺对RGF性能的影响;针对已经回收的RGF,重点总结了硅烷偶联剂改性、酸/碱改性、等离子体改性及涂层改性等表面改性方法的作用机制与应用效果,分析了各类方法在恢复纤维表面活性、改善界面结合性能和提升复合材料性能方面的作用;并阐述了RGF在催化/吸附载体、复合材料制造和建筑材料等领域的应用进展。研究发现,化学溶解法在保持纤维形貌与力学性能方面优势明显,硅烷偶联与涂层改性在界面增强方面具有较好的工程应用基础,建筑材料和中低端复合材料是当前较成熟的利用方向,而催化剂、吸附剂等功能载体和高性能复合材料则是未来高值化发展的路径。

       

      Abstract: With the continuous expansion of installed wind power capacity and the gradual decommissioning of early wind turbines, the generation of waste wind turbine blades has been increasing rapidly. Wind turbine blades are primarily composed of glass fiber-reinforced resin composites, which are characterized by poor degradability, difficulty in separation, and significant potential for resource utilization. Enhancing their resource value has become an important research direction in the treatment of wind power solid waste. This paper focuses on the high-value utilization of recycled glass fibers (RGF) from waste wind turbine blades, and discusses the effects of different recycling processes on the properties of rGF. For the RGF, various surface modification methods—including silane coupling agent modification, acid/alkali modification, plasma modification, and coating modification—are systematically summarized in terms of their mechanisms and application performance, and their roles in restoring fiber surface activity, improving interfacial bonding performance, and enhancing composite properties are analyzed. Furthermore, the application progress of RGF in fields such as catalytic/adsorptive carriers, composite manufacturing, and construction materials is elaborated. The results indicate that chemical dissolution methods exhibit significant advantages in preserving fiber morphology and mechanical properties, while silane coupling and coating modifications have solid practical foundations for engineering applications in interfacial reinforcement. At present, construction materials and low-to-medium grade composites represent relatively mature application directions, whereas functional carriers (e.g., catalysts and adsorbents) and high-performance composites are promising pathways for future high-value utilization.

       

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