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    储能锂电池有价金属高效浸取回收研究进展

    Research progress on efficient leaching and recovery of valuable metals from energy storage lithium batteries

    • 摘要: 在“双碳”目标的驱动下,退役锂离子电池的高效、低碳、高值化回收已成为构建新能源产业链绿色闭环的关键环节。然而,当前回收工艺仍面临锂选择性低、酸碱耗量高、残渣难利用三大核心瓶颈,制约了其规模化与绿色化发展。为应对上述挑战,研究领域已逐步形成多路径协同攻关的态势,并涌现出一系列新兴回收方法和直接再生方法。在正极材料回收方面,低共熔溶剂法作为一种绿色温和的冶金技术,能有效替代传统强酸,显著降低二次污染;CO2靶向提锂技术通过构建碳化体系,实现了锂元素的高选择性回收,为破解锂回收率低的难题提供了新思路;熔盐焙烧法利用熔盐介质的独特性质,在相对低温下实现正极材料的转化,兼具低能耗与高金属回收率的优点;以煤粉或生物质为还原剂的碳热还原法,在实现有价金属还原的同时,降低了工艺碳足迹;而新兴的接触电催化技术则通过液固接触起电效应诱导的氧化还原反应,为金属的深度、高效回收开辟了全新的技术路径。在正极材料直接再生利用方面,修复再生技术通过对失效正极材料进行化学再锂化与结构重构,使其电化学性能得以恢复,为实现电池材料的闭环循环与高值化利用提供了更具经济潜力的解决方案。这些方法在提升金属回收率、产物纯度与过程绿色能效方面展现出巨大潜力,正推动电池回收技术向环境友好、经济可行的方向演进。系统梳理了包括火法冶金、湿法冶金在内的常规回收技术和修复再生技术,并重点综述了以低共熔溶剂、CO2靶向提锂、熔盐焙烧、碳热还原、接触电催化及修复再生为代表的新兴回收和直接再生方法的最新研究进展。通过分析比较各类技术的优势、局限与研究脉络,旨在为退役锂离子电池,特别是正极材料的资源化利用提供全面的技术视角,并对其未来发展趋势与面临的挑战进行展望,以期为推动该领域的科技创新与产业升级提供参考。

       

      Abstract: Driven by the Dual Carbon Goals, the efficient, low-carbon, and high-value recycling of end-of-life lithium-ion batteries has become a critical link in establishing a green closed-loop for the new energy industry chain. However, current recycling processes still face three core bottlenecks: low lithium selectivity, high acid/alkali consumption, and difficult-to-utilize residues, which constrain their large-scale and green development. To address these challenges, the research community has adopted a multi-path collaborative approach, yielding a series of emerging recycling methods and direct regeneration techniques. For cathode material recovery, the deep eutectic solvents—a green, mild metallurgical technique—effectively replaces traditional strong acids, significantly reducing secondary pollution. CO2-targeted lithium extraction technology achieves highly selective lithium recovery by constructing carbonization systems, offering novel solutions to low recovery rates; Molten salt roasting leverages the unique properties of molten salt media to convert cathode materials at relatively low temperatures, combining low energy consumption with high metal recovery rates; The carbon thermal reduction method, using pulverized coal or biomass as reducing agents, reduces the process carbon footprint while achieving reduction of valuable metals; the emerging contact-electro-catalytic technology, through redox reactions induced by the electrostatic effect of liquid-solid contact, opens up a new technical pathway for deep and efficient metal recovery. Regarding direct recycling of cathode materials, repair and regeneration technologies restore electrochemical performance by chemically relithiuming and structurally reconstructing spent cathodes, offering economically promising solutions for closed-loop recycling and high-value utilization of battery materials. These approaches demonstrate significant potential in enhancing metal recovery rates, product purity, and green process efficiency, driving battery recycling technology toward environmentally friendly and economically viable solutions. This paper systematically reviews conventional recycling technologies—including pyrometallurgy and hydrometallurgy—alongside direct regeneration techniques. It focuses on recent advancements in emerging recycling and direct regeneration methods, such as deep eutectic solvents, CO2-targeted lithium extraction, molten salt roasting, carbon thermal reduction, contact-electro-catalysis, and repair and regeneration. By analyzing the advantages, limitations, and research trajectories of various technologies, this paper aims to provide a comprehensive technical perspective for the resource utilization of end-of-life lithium-ion batteries, particularly cathode materials. It also outlines future development trends and challenges, seeking to offer insights for advancing technological innovation and industrial upgrading in this field.

       

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