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    污泥水热炭活化吸附矿区酸性土壤重金属的工艺

    Process of heavy metals adsorption in acidic mining area soil by activated sludge hydrochar

    • 摘要: 修复酸性矿区重金属污染土壤的常见方法是使用包括熟石灰和生物炭等的综合土壤修复剂进行治理,能够有效缓解土壤酸性并固定土壤重金属。使用生物炭尤其是水热炭能够同时修复土壤酸性和吸附固定重金属,但水热炭的孔隙特性和表面官能团活性需要定向活化提升以强化重金属吸附能力。本研究从土壤酸性治理和重金属吸附固定的需求出发,设计了物理活化和化学活化相结合的水热炭活化工艺,有效强化了污泥水热炭的孔隙结构和提升了表面官能团含量,以强化水热炭对矿区常见重金属的吸附固定作用,同时本研究探索了Ca(OH)2和CaCO3作为活化剂以减少常见活化方式带来的高成本活化剂投入费用和外源金属离子进一步污染土壤的风险。实验结果表明,活化后的污泥水热炭对锌、铜、铅、镉和铬的吸附量显著提高,对铬的吸附量最高可达85.09 mg/g,同时,使用常见土壤修复剂配方之一的熟石灰作为活化剂能够进一步提高化学品的利用率。污泥水热炭活化工艺的成本分析表明,活化工艺使用的活化剂成本较少,环境风险较小,活化工艺具有较低的运行成本,本研究为污泥水热炭的定向活化和酸性矿区土壤重金属修复剂的开发提供了一种绿色、高效、经济的解决方案。

       

      Abstract: A common method for remediating heavy metal contaminated soil in acidic mining areas is to use comprehensive soil remediation agents, including slaked lime and biochar, which can effectively alleviate soil acidity and immobilize soil heavy metals. The use of biochar or hydrochar can simultaneously remediate soil acidity and adsorb and immobilize heavy metals, but the pore properties and surface functional group activity of hydrochar need to be enhanced by targeted activation to strengthen the heavy metal adsorption capacity. A hydrochar activation process combining physical activation and chemical activation was designed from the needs of soil acidity treatment and heavy metal adsorption and immobilization, which effectively strengthened the pore structure of the sludge hydrochar and enhanced the surface functional group content to strengthen the adsorption and immobilization of common heavy metals in the mining area, and at the same time, Ca(OH)2 and CaCO3 were explored as the activators to reduce the high cost and the risk of further soil contamination by exogenous metal ions brought by common activation methods. The experimental results showed that the activated sludge hydrochar significantly increased the adsorption of zinc, copper, lead, cadmium and chromium, and the adsorption of chromium could reach up to 85.09 mg/g. At the same time, the use of slaked lime, which is one of the common soil remediation agent formulations, as an activator could increase the utilization rate of the chemicals. The cost analysis of the sludge hydrochar activation process showed that the activator used in the activation process cost less, the environmental risk was smaller, and the activation process had lower running cost. A green, efficient and economic solution for the targeted activation of sludge hydrochar and the development of heavy metal remediation agent for acid mine soil is provided.

       

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