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    中石化典型地区气化炉渣基础物性分析研究

    Analysis and research on basic physical properties of gasification slag in representative areas of Sinopec

    • 摘要: 随着煤炭资源高值转化技术的不断开发与升级,气化渣是我国近年来产生的重要固废,年产生量巨大,对环境造成严重的污染。针对气化渣的资源属性,目前以低端建工建材和高端陶瓷等铝硅复合材料制备两大方面为主,但随着我国基础设施建设日趋完善,建工建材利用日趋饱和,因此气化渣高值转化利用成为当前的研究热点。但因缺乏对气化渣自身元素/物质组成的稳定性、赋存状态等方面的认识,目前多数复合材料制备处于实验室研究阶段,尚不足以实现工业化生产。以中石化不同地区气化渣为原料,分别考察不同地区细渣/粗渣的元素组成、物质组成、微观形貌及元素赋存形态,明确气化渣以铝硅酸盐玻璃体(约40%)和无定型碳颗粒(5%~50%)为主,铝硅含量总量在40%左右,铁钙含量在20%~40%,大部分钙铁与其形成共熔体,少部分钙铁单独存在;细渣和粗渣的主要区别在于粗渣颗粒含碳量(5%~20%)比细渣(20%~50%)低,细颗粒含碳量高,粗颗粒玻璃相反应活性高于细渣。

       

      Abstract: With the continuous development and upgrading of high-value conversion technologies for coal resources,gasification slag has a huge annual output and causes serious pollution to the environment as an important solid waste produced in China in recent years. In view of the resource characteristics of gasification slag,it is currently mainly used to prepare low-end building materials and high-end ceramics and other aluminum-silicon composite materials. However,the market for construction and building materials utilization has become increasingly saturated with the improvement of Chinese infrastructure construction,so the high-value conversion and utilization of slag has become a current main research hotspot. However,due to the lack of knowledge about the stability and occurrence of the element/material composition of the gasification slag,the preparation of most composite materials is currently in the laboratory research stage,which is not enough to realize industrial production. In response to the above problems,gasification slag from four different regions was selected as the raw material for this article,and the element composition,material composition,micro morphology and element occurrence forms of fine slag/coarse slag in different regions were studied. It can be seen that the gasification slag is mainly composed of aluminosilicate glass (≈40%) and amorphous carbon particles (5%-50%). The total content of aluminum and silicon is about 40%,and the content of iron and calcium is 20%-40%; Most of the calcium and iron form a eutectic with it,and only a small amount of calcium and iron exist alone.The main difference between the fine slag and the coarse slag is that the content of carbon in coarse slag (5%-20%) is lower than that in fine slag (20%-50%),the carbon content of fine slag is higher,and the glass phase reactivity is higher than that of the fine slag.

       

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