高级检索

    高含氯脱硫石膏制备石膏砂浆研究进展

    Research progress on the preparation of gypsum mortar from desulfurization gypsum with high chlorine content

    • 摘要: 湿法脱硫是燃煤烟气脱硫的主流技术,该过程会产生大量脱硫石膏,制备砂浆等绿色建材产品是其资源化利用的重要途径。但由于脱硫系统工艺水循环使用,加之脱硫废水零排放要求,使脱硫石膏中氯离子含量较高,严重影响石膏砂浆性能。因此,对高含氯脱硫石膏中氯离子进行控制,以抑制其对石膏砂浆制品性能的不利影响,已成为当前研究热点。介绍了氯离子对石膏砂浆的作用机理,包括对石膏水化过程、吸水性能的影响等。对目前氯离子的控制技术做出系统梳理,包括物理层面吸附氯离子及堵塞氯离子迁移孔道,以及化学层面转化成氯铝酸盐。此外,对高含氯石膏砂浆的制备条件进行了总结,其中,脱硫石膏在150~180℃下煅烧1.5~2.5h,得到的脱硫建筑石膏具有较高的致密度以及较低的孔隙率,可阻碍氯离子迁移;缓凝剂能延长凝结时间,但不利于氯离子迁移的控制;保水剂能够提高石膏砂浆保水性,但会加快氯离子迁移;减水剂可降低水灰比,抑制氯离子迁移;防水剂改善了孔隙结构,抑制了砂浆表面氯化钙的生成。并对未来采用高氯脱硫石膏制备石膏砂浆的发展趋势进行了展望。

       

      Abstract: Wet flue gas desulfurization (WFGD) is the key technology for the desulfurization of flue gas in coal-fired power plants,which will produce a large amounts of desulfurization gypsum,and the preparation of green building materials,such as gypsum mortar,is an important way for their high-value utilization. However,due to water recycling in the desulfurization system and the requirement for zero discharge of desulfurization wastewater,the content of chloride ions in desulfurization gypsum is generally high,which seriously restricts the quality of gypsum mortar. Therefore,it has become a current research hotspot to control the chloride ions in desulfurized gypsum in order to suppress its adverse effects on the performance of gypsum mortar products. Firstly,the influence of chloride ions on gypsum mortar was introduced in detail,including the effects of Cl-on the hydration process of gypsum and its performance of water absorption. Then,the current control technology of chloride ions was systematically introduced,including physically adsorbing chloride ions and blocking the channels of chloride ion migration,and chemically converting to the water-insoluble chloroaluminate. In addition,the detailed preparation parameters of gypsum mortar from WFGD gypsum with high chloride ion contents were summarized. When the calcination temperature is 150-180 ℃ and the duration is 1.5-2.5 hours,the obtained gypsum has higher density and lower porosity,which can hinder the migration of chloride ions. Retarder can prolong the setting time of gypsum,but it is not conducive to the control of chloride ions migration. Waterretention agent can improve the water retention of gypsum mortar but will accelerate the migration of chloride ions. Superplasticizer can decrease the water/ash ratio,which can suppress the migration of chloride ions. Water-proofing agent can improve the pore structure of the gypsum,which inhibits the formation of calcium chloride. Finally,the developing trend of gypsum mortar preparation from WFGD gypsum with high chlorine ions was also proposed.

       

    /

    返回文章
    返回