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    30万m3/h电厂烟气碳捕集系统能流特征与热量耗散途径

    Energy flow characteristics and heat dissipation pathways of a 300 000 m3/h flue gas carbon capture system for power plant

    • 摘要: 介绍30万Nm3/h电厂烟气碳捕集系统与电厂热力系统物质与能量耦合原理。分析典型工况下碳捕集系统的物质流与能量流全过程,明确煮沸热耗散于物流显热(45.10%)和再生工艺热(54.90%)的份额,以及再生工艺热中化学反应热(70.14%)和汽化潜热(29.86%)的份额。在5种冷却耗散途径中,再生气冷却器5热量品位最高(等级80 ℃),耗散占比9.13%,其次为热量品位第2(等级60 ℃)、占比最大26.77%的贫液进吸收塔冷却器4,二者可相互转化,是余热利用的关键环节。研究改变碳捕集率和保持碳捕集率调整不同因素(富液分流、贫富液换热端差、贫液负载、吸收剂浓度及比例(MEA:MDEA)等)对冷却耗散和潜显热耗散比的影响规律。结果表明仅调整碳捕集率不会影响潜显热耗散比(0.34),富液分流可显著改变潜显热耗散比,自富液分流比例0.05下的0.63快速下降至0.20下的0.11。缩小贫富液换热端差可快速提高潜显热耗散比,可从12 ℃端差下的0.22提高至6 ℃下的0.44。贫液负载从0.19上升至0.28时,潜显热耗散比从0.48下降到0.12。提高吸收剂比例后(0.5~2.0),再生过程中水分蒸发需求扩大,潜显热耗散比显著增加(从0.11快速上升至0.65)。

       

      Abstract: This article introduces the material and energy coupling principle between the 300 000 Nm3/h power plant flue gas carbon capture system and the power plant thermal system. The entire process of material and energy flow in carbon capture systems under typical operating condition is analyzed. The proportion of boiling heat dissipation in the sensible heat of the material flow (45.10%) and the heat of the regeneration process (54.90%), as well as the proportion of chemical reaction heat (70.14%) and latent heat of vaporization (29.86%) in the heat of the regeneration process, are clarified. Among the five cooling dissipation pathways, the regeneration gas cooler 5 has the highest heat grade (grade 80 ℃), accounting for 9.13% of the dissipation. The second heat grade (grade 60 ℃), with the largest proportion of 26.77%, is the lean liquid entering the absorption tower cooler 4. The two can be converted into each other and are the key to waste heat utilization. The influence of only adjusting carbon capture and different factors (rich liquid diversion, lean-rich liquid heat exchange end difference, lean liquid load, absorbent concentration and proportion (MEA: MDEA), etc.) on cooling dissipation and latent to sensible dissipation ratio (cooler 5 to cooler 4) is studied. Only adjusting the carbon capture rate will not affect the latent to sensible dissipation ratio (0.34), while the rich liquid diversion can significantly change the latent to sensible dissipation ratio, with a rapid decrease from 0.63 at a rich liquid diversion ratio of 0.05 to 0.11 at 0.2. Reducing the lean-rich liquid heat exchange end difference can quickly increase the latent to sensible dissipation ratio from 0.22 at 12 ℃ end difference to 0.44 at 6 ℃. When the lean liquid load increases from 0.19 to 0.28, the latent to sensible heat dissipation ratio decreases from 0.48 to 0.12. After enhancing the absorbent proportion (0.5−2.0), the demand for water evaporation during the regeneration process increase, so the latent to sensible heat dissipation ratio significantly increased (rapidly rising from 0.11 to 0.65).

       

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