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    10 MWel级循环流化床生物质空气气化气固产物特性

    Gas-solid product characteristics of 10 MWel circulating fluidized bed biomass air gasification

    • 摘要: 为了反应器设计和运行参数优化与生物质半焦的增值利用,在气化试验的基础上分析了稻壳气化的燃气成分、产气参数,使用多种方法表征分析了生物质半焦的表面形貌、物理特征和碳质结构。燃气分析结果表明:燃气中CO的体积分数最高,大约为18%,H2的体积分数为7%左右,燃气热值为5.48 MJ/m3左右,属于低热值燃气。稻壳半焦的物理特征分析表明:半焦的主要元素为C、O、Si和K。半焦的BET比表面积为21.7742 m2/g;小部分粒径为1~10 μm和100~300 μm,大多数粒径为10~100 μm。半焦多数孔是孔径为2~10 nm的中孔,并且存在少量微孔和大孔,平均孔径为7.0496 nm,总孔体积为0.050907 cm³/g。X射线衍射分析说明半焦含有石英晶型的SiO2,碳的无序性较高,石墨化程度低。红外光谱分析说明半焦的大分子结构含有—OH、C=C和C—O键等官能团。拉曼光谱分析表明半焦含有石墨结构,D1峰与G峰的强度比(ID1/IG)为7.93,半焦的碳质结构有较高含量的缺陷碳和无定形碳结构。

       

      Abstract: In order to optimize the design and operation parameters of the reactor and the value-added utilization of biomass char, the gas composition and gas production parameters of rice husk gasification were analyzed on the basis of gasification test. The surface morphology, physical characteristics and carbon structure of biomass char were characterized and analyzed by various methods. The results of gas analysis show that the volume fraction of CO in gas is the highest, about 18%, the volume fraction of H2 is about 7%, and the calorific value of gas is about 5.48 MJ/m3, which belongs to low calorific value gas. The analysis of the physical characteristics of rice husk char shows that the main elements of char are C, O, Si and K. The BET specific surface area of char is 21.7742 m2/g. A small part of the particle size is 1-10 μm and 100-300 μm, most of the particle size is 10-100 μm. Most of the pores of the char are mesopores with a pore size of 2-10 nm, and there are a small number of micropores and macropores. The average pore size is 7.0496 nm, and the total pore volume is 0.050907 cm3/g. X-ray diffraction analysis shows that the char contains quartz crystal SiO2, the disorder of carbon is high, and the degree of graphitization is low. The infrared spectrum analysis shows that the macromolecular structure of the char contains functional groups such as —OH, C=C and C—O bonds. Raman spectrum analysis showed that the semi-coke contained graphite structure, the intensity ratio (ID1/IG) of D1 peak to G peak was 7.93, and the carbonaceous structure of char has a high content of defective carbon and amorphous carbon structure.

       

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