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    聚光太阳能–生物质–天然气协同热化学制氢与高效碳捕集

    Synergistic thermochemical hydrogen production and high-efficiency carbon capture via concentrated solar energy, biomass, and natural gas

    • 摘要: 面向稠油热采过程中高温蒸汽需求量大、化石燃料消耗多和碳排放强度高等问题,综述了聚光太阳能−生物质−天然气协同热化学制氢与碳管理体系的研究进展。围绕稠油热采对蒸汽、氢气和 CO2 协同利用的场景需求,首先基于能的梯级利用原则,介绍了多能协同系统的热力学分析框架。进一步地,系统梳理了太阳能驱动热化学转化、生物质气化/热解、天然气重整及其多能耦合构型,指出现有集成路径主要包括串联型与循环型:前者通过气化或热解−重整衔接提升合成气品质,后者依托金属氧化物氧化还原循环实现能量储存与碳捕集协同。在各自文献设定的原料类型、反应器构型、运行工况和系统边界下,代表性研究显示:太阳能驱动生物质气化系统的一次能源效率可达44.63%,太阳能份额可达29.59%;部分实验室化学链装置的CO2捕集率为82.5%~96.0%;富氧燃烧烟气经冷却和冷凝脱水后可形成CO2富集干烟气,其组成受燃料类型、供氧纯度、漏风、烟气循环及净化边界影响。上述数据分别对应特定系统设计工况、试验装置或烟气处理边界,主要用于展示相关技术的性能量级和发展潜力,不用于不同路线之间的直接性能排序。总体而言,该体系的关键在于太阳热、生物质和天然气在高温反应驱动、稳定补能、负荷调节和碳流组织中的合理分工,以及反应、换热、分离、压缩和油田端利用过程之间的梯级衔接。未来需进一步推进高效反应器、储热与变工况调控、产物原位分离、化学链耦合及面向稠油热采场景的系统评价。

       

      Abstract: To tackle the high steam demand, heavy fossil fuel consumption and high carbon emissions in heavy oil thermal recovery, research progress in concentrated solar energy–biomass–natural gas synergistic thermochemical hydrogen production and carbon management systems is reviewed. Guided by the cascade energy utilization principle, it first introduces the thermodynamic analysis framework for multi-energy complementary systems targeting the coordinated demand for a steam, hydrogen and CO2 in heavy oil thermal recovery. It then summarizes solar-driven thermochemical conversion, biomass gasification/pyrolysis, natural gas reforming and their coupling configurations, which are mainly divided into series and cyclic modes: the former upgrades syngas via gasification/pyrolysis-reforming coupling, while the latter combines energy storage with carbon capture through metal oxide redox cycles. Representative studies show that solar-driven biomass gasification achieves a primary energy efficiency of 44.63% and a solar fraction of 29.59%; lab-scale chemical looping units reach 82.5%–96.0% CO2 capture efficiency; oxy-fuel combustion flue gas can be enriched into dry CO2 stream after cooling and dehydration, with its composition affected by multiple operating factors. These data reflect performance levels under specific conditions and are not for direct cross-route comparison. Overall, the system hinges on rational matching of solar heat, biomass and natural gas in reaction driving, load regulation and carbon flow organization, as well as cascade integration across unit processes. Future work should focus on high-efficiency reactors, thermal storage and off-design regulation, in-situ separation, chemical looping integration, and scenario-specific system evaluation for heavy oil thermal recovery.

       

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