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    可凝结颗粒物研究进展

    Research advance in condensable particulate matter

    • 摘要: 燃烧源颗粒物的控制一直是大气污染防控领域的重点问题。颗粒物包括可过滤颗粒物(FPM)和可凝结颗粒物(CPM)。FPM就是被广泛认知的烟尘,其控制技术已较为成熟,治理效果已经达到超低排放的水平;而CPM是指在烟道内呈现气态并在排放后因降温冷凝等作用转化成颗粒的物质,虽然目前CPM尚未被列入强制治理的范围,但其环境影响及潜在危害已经越来越引起重视,相关研究逐渐成为新的热点。系统综述了近年来CPM的最新研究进展:在环境影响方面,最新的定量分析显示CPM对大气中的有机气溶胶和PM2.5有重要贡献,应给予足够重视;在CPM测量方面,现有冲击瓶冷却法和稀释冷却法虽然历经改进,但其设备和操作复杂、数据实时性差、误差因素多等缺陷,严重影响了便捷性和准确性;CPM在线检测技术取得突破,但有待进一步优化;最新的CPM排放数据显示:某些排放源的CPM排放浓度已经超过FPM,CPM包含复杂的有机和无机组分,CPM凝结后形成超细颗粒物;CPM的生成机理研究取得进展:燃料中的硫、氯、氮等元素及烟气中水蒸气、硫氧化物、氮氧化物等物质影响CPM无机组分的含量,而CPM的有机组分受燃料特性、燃烧条件、燃烧充分程度等因素的影响;在CPM控制方面,大量研究聚集于现有大气污染物治理设备对CPM的协同脱除,也发展了烟气冷却法、吸附法和燃料混燃法3种CPM控制方法,但这些方法的效率有待提高。未来应进一步探明CPM的环境影响、发展可靠的CPM在线检测技术、揭示CPM生成机理、开发CPM高效控制技术,全面推进CPM污染防控的理论研究和工程实践。

       

      Abstract: The control of particulate matter from combustion sources has always been a key issue in the field of air pollution prevention and control. Particulate matter includes filterable particulate matter (FPM) and condensable particulate matter (CPM). FPM refers to soot. Its control technology has become relatively mature and its treatment effect has reached the level of ultra-low emissions. CPM refers to substances that exist in a gaseous state in the flue and are converted into particles by cooling and condensation after discharge. Although CPM has not yet been included in the scope of mandatory governance, its environmental impact and potential hazards have been increasingly valued, and related research has gradually become a new hotspot. This paper systematically reviews the latest research progress of CPM in recent years: In terms of environmental impact, the latest quantitative analysis shows that CPM makes important contributions to organic aerosols and PM2.5 in the atmosphere, and should be given sufficient attention; In terms of CPM measurement, although the existing impinger cooling method and dilution cooling method have undergone improvements, their equipment and operation are complex, the real-time data is poor, and there are many error factors, which seriously affect the convenience and accuracy; CPM online measurement technology has made breakthroughs, but further optimization is needed; The latest CPM emission data shows that the CPM emission concentration of some emission sources has exceeded FPM. CPM contains complex organic and inorganic components, and after condensation, it forms ultrafine particles; Research on the formation mechanism of CPM has made progress: elements such as sulfur, chlorine, and nitrogen in the fuel, as well as substances such as water vapor, sulfur oxides, and nitrogen oxides in the flue gas, affect the content of inorganic components in CPM, while the organic components of CPM are influenced by factors such as fuel characteristics, combustion conditions, and combustion adequacy; In terms of CPM control, a large amount of research has focused on the collaborative removal of CPM by existing air pollutant treatment equipment, and three CPM control methods have also been developed: flue gas cooling, adsorption, and fuel mixing. However, the efficiency of these methods needs to be improved. In the future, we should further explore the environmental impact of CPM, develop reliable CPM online detection technology, reveal the formation mechanism of CPM, develop efficient control technology for CPM, and comprehensively promote the theoretical research and engineering practice of CPM pollution prevention and control.

       

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