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    生物质气化气催化提质研究进展

    Research progress on catalytic upgrading of biomass producer gas

    • 摘要: 生物质能作为碳中性的可再生能源,气化技术是其规模化利用的核心路径之一。生物质气化气催化提质通过组分定向转化和杂质高效脱除,可实现高值化,并具有温度范围宽、产物纯度高、与可再生能源系统易耦合等优点。根据生物质气化气的组成特点,按照H2、合成气(CO+H2)、烃类、CO2以及污染物进行组分切割,系统综述催化技术在包括提纯制氢、合成气组分转化、烃类组分重整、CO2捕集转化以及污染物协同脱除等5类生物质气化气提质路径的研究现状。研究揭示,各类路径均高度依赖催化剂活性相、载体与助剂的协同作用机制。制氢路径中,Ni基催化剂经CeO2/Fe2O3修饰可显著提升抗积碳性能;合成气转化则依据n(H2)/n(CO)比差异,分别适配倾向低碳烯烃的Fe基催化剂与倾向长链烷烃的Co基催化剂;烃类重整聚焦CH4与焦油转化,通过双金属协同与介孔限域效应提升稳定性;CO2捕集虽已形成Ca基、胺基及MOFs三类材料体系,但捕集与转化过程的集成度仍较低;污染物脱除在单一硫、氮化合物处理上效率显著,却缺乏多污染物协同脱除的有效方案。未来研究可聚焦于多功能催化剂理性设计、氧空位与界面效应调控等创新技术路径,以解决处理能力不足、过程集成度偏低、催化剂稳定性差等瓶颈。

       

      Abstract: As a carbon-neutral renewable energy source, biomass gasification technology represents one of the core pathways for its large-scale utilization. Catalytic upgrading of biomass producer gas achieves high-value conversion through targeted component transformation and efficient impurity removal, offering advantages such as a wide operating temperature range, high product purity, and easy integration with renewable energy systems. Based on the composition characteristics of biomass producer gas, the components are separated into H2, synthesis gas (CO+H2), hydrocarbons, CO2, pollutants. This systematic review summarizes the current research status of catalytic technologies across five pathways for upgrading biomass producer gas: hydrogen purification and production, synthesis gas component conversion, hydrocarbon reforming, CO2 capture and conversion, and synergistic pollutant removal. Research reveals that all pathways highly depend on the synergistic mechanism among the active phase, support, and additives of catalysts. In hydrogen production pathways, CeO2/Fe2O3−modified Ni-based catalysts significantly enhance coking resistance. For syngas conversion, Fe-based catalysts favoring low-carbon olefins and Co-based catalysts favoring long-chain alkanes are respectively adapted based on differences in n(H2)/n(CO) ratios. Hydrocarbon reforming focuses on CH4 and tar conversion, enhancing stability through bimetallic synergy and mesoporous confinement effects. Although CO2 capture has established three material systems: Ca-based, amine-based, and MOFs-integration of capture and conversion processes remains relatively low. Pollutant removal demonstrates high efficiency in treating single sulfur or nitrogen compounds but lacks effective solutions for synergistic removal of multiple pollutants. Future research may focus on innovative technical approaches such as rational design of multifunctional catalysts and regulation of oxygen vacancy and interfacial effects to address bottlenecks including insufficient processing capacity, low process integration, and poor catalyst stability.

       

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