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    含铬污染物治理与修复及铬资源循环利用研究进展

    Progress in chromium pollution control and resource recycling

    • 摘要: 铬及其化合物作为重要的化学原料,广泛应用于电镀、皮革鞣制及催化等多个工业领域。然而,随着工业的快速发展,铬污染已成为重要的环境问题之一,铬(Ⅵ)具有较强毒性,可通过呼吸道、消化道及皮肤等途径被人体吸收,危害健康。因此,亟需对铬污染进行有效的治理与修复。目前,含铬废水的治理方法主要包括物理法、化学法和生物法,旨在有效去除或转化体系中的铬离子,从而降低其对环境和人类健康的潜在危害。Cr(Ⅲ)虽为相对稳定形态,但在特定条件下可能转化为毒性更强的Cr(Ⅵ),因此其治理与修复同样具有重要的环境意义。而对于含铬固废的处理,则主要采用稳定化、热处理以及资源化利用等方式,其处理效果受铬的价态等多重因素影响。近年来研究发现,利用层状双金属氢氧化物(LDHs)材料可通过同晶取代将重金属铬离子固定,形成更稳定的超稳矿化结构,从而显著降低其在环境中的迁移性和生物有效性,为水体和土壤修复提供了新途径。此外,开发低毒性或无铬替代材料亦被视为重要方向,部分过渡金属在电镀、皮革鞣制及催化等领域已展现出一定的替代潜力。值得注意的是,LDHs在铬资源替代方面也表现出应用优势,如在耐腐蚀涂层及传统催化等领域展现出良好的发展前景。系统总结了目前针对含铬废水/固废的主要处理技术及其优缺点,并且介绍了铬资源回收与替代策略的研究进展,为未来含铬污染治理提供理论支撑和技术参考。

       

      Abstract: Chromium and its compounds are important chemical raw materials used in various industrial fields such as electroplating, leather tanning, and catalysis. However, with the rapid development of industry, chromium pollution has become one of the important environmental issues. Chromium(Ⅵ) has strong toxicity and can be absorbed by the human body through respiratory, digestive, and skin pathways, posing a health hazard. Therefore, it is urgent to effectively control and restoration chromium pollution. At present, the treatment methods for chromium containing wastewater mainly include physical, chemical, and biological methods, aiming to effectively remove or transform chromium ions in the system, thereby reducing their potential harm to the environment and human health. Although Cr(Ⅲ) is a relatively stable form, it may transform into more toxic Cr (Ⅵ) under specific conditions, so its control and restore have important environmental significance. For the treatment of chromium containing sludge, stabilization, heat treatment, and resource utilization are mainly used, and the treatment effect is influenced by multiple factors such as the valence state of chromium and so on, in recent years, research has found that the use of layered double metal hydroxides (LDHs) materials can fix heavy metal chromium ions through eutectic substitution, forming a more stable ultra stable mineralization structure, significantly reducing their mobility and bioavailability in the environment, providing a new approach for the remediation of water bodies and soils. In addition, the development of low toxicity or chromium free alternative materials is also considered an important direction, and some transition metals have shown certain substitution potential in fields such as electroplating, leather tanning, and catalysis. It is worth noting that LDHs demonstrate application advantages in chromium resource substitution, such as showing good development prospects in corrosion-resistant coatings and catalysts. This article systematically reviews the main treatment technologies and their advantages and disadvantages for chromium containing wastewater and sludge, and introduces the research progress on chromium resource recovery and substitution strategies, providing theoretical support and technical reference for future chromium pollution control.

       

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