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    电与光驱动绿氢制备技术:原理、挑战与规模化应用路径

    Green hydrogen preparation driven by electricity and light: principles, challenges, and paths to scaling up

    • 摘要: 氢气作为一种能量密度高、燃烧产物零碳排放的清洁能源载体,在未来能源系统中具有不可替代的核心地位。在全球能源结构转型与“双碳”目标的战略背景下,开发可持续的可再生能源制氢技术是应对能源危机与气候变化的关键路径。然而,当前主流制氢工艺(如蒸汽甲烷重整)高度依赖化石燃料,伴随显著的二氧化碳排放,制约了其环境效益。因此,基于可再生能源(如绿电和光能)驱动的“绿氢”制备技术成为研究焦点。从原理、挑战及规模化潜力视角,系统综述了3类可再生能源制氢技术:①电解水制氢作为目前最成熟的“绿氢”制备技术,兼具快速启停、负载响应灵活的特点,可适配波动性强的风电、光伏等可再生能源制氢,从而有效实现可再生能源的消纳与储存。电解水制氢包括碱性水电解槽、质子交换膜电解槽、阴离子交换膜电解槽和固体氧化物电解槽,各具技术特点。其核心瓶颈为高电耗导致的成本问题,与可再生能源耦合被视为降低电力成本的核心路径,随着可再生能源发电成本及电解槽成本的不断降低,绿氢成本有望实现平价。②光催化分解水制氢可直接利用太阳能驱动水分解,具有理论优势,但面临太阳能–氢能转换效率低的挑战,开发高效、稳定的光催化剂是突破关键。③光电化学分解水制氢结合了光化学与电化学分解的优势,潜力巨大,但转换效率仍需大幅提升,开发大面积、高效、稳定且低成本的光电极材料是当前研究的核心任务。此外,3种制氢技术的规模化应用对能源改革起着重要的作用,详细探讨了3种制氢技术的规模化路径。最后,从原料(水)高效活化与利用、过程能耗优化控制、单位产能提升3个维度探讨了技术创新方向,并展望了未来研究重点。当前水分解制氢技术对原料水纯度要求较高,需先经水质预处理,额外增加成本投入;全球淡水资源短缺、地域分布不均,进一步制约了纯水制氢技术的规模化应用。利用大气集水的分布式制氢技术以及直接海水电解制氢技术可从根本上避免该问题。另一方面,降低制氢成本以及提高制氢系统的能量利用效率也至关重要。这些讨论旨在为推动高效、经济、可持续的“绿氢”技术发展提供参考。

       

      Abstract: Hydrogen, as a clean energy carrier with high energy density and zero carbon emissions from combustion products, has an irreplaceable central position in the future energy system. In the strategic context of global energy structure transformation and dual carbon goals, the development of sustainable renewable energy hydrogen production technology is a key path to cope with the energy crisis and climate change. However, current mainstream hydrogen production processes (such as steam methane reforming) are highly dependent on fossil fuels, accompanied by significant carbon dioxide emissions, which restrict their environmental benefits. Therefore, green hydrogen preparation technologies driven by renewable energy sources (such as green electrical energy and light energy) have become a research focus. Three types of renewable energy hydrogen production technologies are systematically reviewed from the perspectives of principles, challenges, and scale-up potentials: ①As the most mature “green hydrogen” production technology currently available, water electrolysis for hydrogen production features both rapid start-stop capability and flexible load response. It is compatible with hydrogen production using renewable energy sources with strong volatility, such as wind power and photovoltaic power, and can effectively absorb and store renewable energy. Water electrolysis for hydrogen production encompasses alkaline water electrolyzers, proton exchange membrane electrolyzers, anion exchange membrane electrolyzers, and solid oxide electrolyzers, with their respective technical characteristics. The core bottleneck is the cost problem caused by high power consumption, coupling with renewable energy is regarded as a core pathway to reduce electricity costs. With the continuous decrease in the costs of renewable energy power generation and electrolyzers, the cost of green hydrogen is expected to achieve parity. ②Photocatalytic decomposition of water to produce hydrogen can be directly driven by solar energy to decompose water, which is theoretically advantageous. It faces the challenge of low conversion efficiency of solar to hydrogen, so the development of high-efficiency and stable photocatalysts is the key to the breakthrough. ③Photoelectricity chemical decomposition of water to hydrogen combines the advantages of photochemical decomposition and electrochemical decomposition, with great potential. However, the conversion efficiency still needs to be greatly improved, the development of larege-scale, efficient, stable and low-cost photoelectrode materials is the core task of the current research. In addition, the large-scale application of the three hydrogen production technologies plays an important role in energy reform, and then elaborates on the large-scale pathways of these three hydrogen production technologies. Finally, the direction of technological innovation is discussed from the three dimensions of efficient activation and utilization of raw materials (water), optimal control of process energy consumption, and enhancement of output per unit of energy consumption, and the focus of future research is also looked forward to. Currently, water splitting for hydrogen production technology imposes relatively high requirements on the purity of feedwater, necessitating pre-treatment of water quality prior to hydrogen production, which incurs additional cost input. Furthermore, the global shortage of freshwater resources and uneven geographical distribution further restrict the large-scale application of hydrogen production technology based on pure water. Distributed hydrogen production technology using atmospheric water harvesting and direct seawater electrolysis for hydrogen production can fundamentally address this issue. On the other hand, reducing the cost of hydrogen production and improving the energy utilization efficiency of hydrogen production systems are also of crucial importance. These discussions aim to provide references for promoting the development of efficient, economical, and sustainable “green hydrogen” technology.

       

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