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    2种离子液体对水泥窑窑尾烟气CO2吸收特性试验研究

    Experimental investigation on the absorption characteristics of two ionic liquids for CO_2 in cement kiln tail gas

    • 摘要: 随着全球气候变暖趋势不断持续,工业领域的碳减排迫在眉睫。水泥熟料生产工艺中,水泥窑产生大量富含CO2的烟气,浓度高达30%以上。因此,水泥窑窑尾烟气的碳捕集将对工业领域的碳减排具有重要作用。以2种离子液体M4GuAc(四甲基胍醋酸盐)、TMGLac(四甲基胍乳酸盐)为研究对象,分别考察了其在30、50、70 ℃下对纯CO2和水泥窑窑尾模拟烟气中CO2的吸收特性。结果表明,离子液体对纯CO2和水泥窑窑尾模拟烟气中CO2的最大吸收量皆随温度的升高而大幅降低,70 ℃时2种离子液体对纯CO2的最大吸收量小于其在30 ℃时最大吸收量的50%;M4GuAc、TMGLac对水泥窑窑尾模拟烟气中CO2的吸收效果明显劣于对纯CO2的吸收效果,最大吸收量仅为相同工况下2种离子液体对纯CO2最大吸收量的22.3%和20.9%。70 ℃下对离子液体进行5次吸收和再生循环试验结果表明,2种离子液体的吸收性能基本稳定,再生次数对其CO2吸收能力影响不大。

       

      Abstract: With the continuous global warming trend,reducing carbon emission from industry is imminent. In the production process of cement clinker,a large amount of tail gas in which consist over 30% CO_2 is emitted from the cement kiln. Therefore,it will contribute greatly to capture CO_2 from tail gas of cement kilns for carbon emission reduction of industrial field. Taking two ionic liquids,M_4GuAc( tetramethylguanidine acetate) and TMGLac( tetramethylguanidine lactate),as research objects,the absorption characteristics of pure CO_2 and CO_2 in simulated tail gas of cement kiln tail gas at 30 °C,50 °C and 70 °C were investigated. The results show that the maximum absorption capacity for pure CO_2 and CO_2 in simulated flue gas from cement kiln tail by ionic liquids decreases greatly with the increase of working temperature. The maximum absorption capacity of the two ionic liquids at 70 ℃ is 50% less than the maximum absorption capacity of the two ionic liquids at 30 ℃ . The absorption effect of M_4GuAc and TMGLacon CO_2 in simulated tail gas of cement kiln is obviously worse than that of pure CO_2. The maximum absorption of CO_2 by the two ionic liquids is only 22.3% and 20.9% of that of pure CO_2 under the same conditions. The five times absorption and regeneration cycle experiments of two kinds of ionic liquids were carried out at 70℃ . The results show that the absorption properties of the two ionic liquids are basically stable in five experiments,and the regeneration times have little effect on the CO_2 absorption capacity of the two ionic liquids.

       

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