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    甲烷二氧化碳重整镍基催化剂的研究进展

    Research progress of nickel-based catalysts for carbon dioxide reforming of methane

    • 摘要: 甲烷二氧化碳重整制合成气是对甲烷、二氧化碳这2种温室气体资源化利用的有效途径。近年来,研究最多的领域是关于该反应催化剂的开发,其中镍基催化剂的研究最广泛。为了全面了解甲烷二氧化碳重整反应及镍基催化剂的应用,介绍了甲烷二氧化碳重整反应的热力学研究及机理;分析了镍基催化剂的积碳原因及消碳途径;论述了镍基催化剂的载体、助剂、制备方法对催化剂催化性能的影响;最后对镍基催化剂未来的研究方向进行了展望。热力学研究结果显示,高温低压有利于甲烷二氧化碳重整反应的进行;针对甲烷二氧化碳重整反应的机理尚没有统一的定论,不同催化剂应用于该反应,作用机理也不同;镍基催化剂积碳主要由甲烷裂解反应、一氧化碳歧化反应及一氧化碳氧化还原反应产生,为解决积碳问题,从催化剂方面着手,通过调控催化剂性质抑制积碳;载体性质、助剂类型、制备方法不同会对镍基催化剂产生不同作用;镍基催化剂距离工业化应用还有一段距离,在未来发展中可优化催化剂制备条件,深入探究催化剂的积碳机理,理论与实践相结合,进一步探究镍基催化剂的性能。

       

      Abstract: Carbon dioxide reforming of methane is an effective way for the resource utilization of green house gases such as carbon dioxide and methane. In recent years,there has been an increasing interest in the development of the reaction catalysts,especially for nickel-based catalysts.In order to understand the utilization of the reaction and the nickel-based catalysts comprehensively,the thermodynamic research and mechanism of this reaction were introduced; the causes of the carbon deposition and ways of carbon elimination on nickel-based catalysts were analyzed; the influence of supports,promoters and preparation methods of nickel based catalysts on the catalytic performance were discussed. Finally,the prospects for the future research directions of nickel-based catalysts were finally proposed. The thermodynamic results show that high temperature and low pressure are beneficial to the reaction; there is no uniform conclusion on the mechanism of the carbon dioxide reforming of methane,since the mechanisms are also different with different catalysts; the coke deposition over the nickel-based catalysts is mainly produced by methane decomposition,CO disproportionation reaction and CO redox reaction,and carbon deposition can be inhibited by adjusting the properties of catalyst in the reaction; the various properties of support,the type of promoter,and the preparation method have different effects on the nickel-based catalysts; there is still a long way for industrial applications of nickel-based catalysts,and in the future development,the preparation conditions of catalyst can be optimized; the carbon deposition mechanism can be deeply explored; theory and practice can be combined to further explore the performance of nickel-based catalysts.

       

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