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    煤粉着火燃烧过程光学诊断研究发展

    Research progress on the optical diagnostics of pulverized coal ignition and combustion process

    • 摘要: 煤炭作为重要的化石燃料,储量丰富,尽管新能源和可再生能源快速发展,煤炭资源在未来几十年里仍将作为我国一次能源重要组成部分。同时煤炭利用带来很多环境污染问题,因此未来煤炭资源的利用逐渐向高效、低碳、低污染物排放利用方式转变。随着光学技术的不断发展,涌现出多种适用于煤粉燃烧诊断的原位非接触式光学诊断技术,极大地促进了燃烧学的发展,为煤炭的清洁高效利用提供了更多实验手段。本文介绍了国内外一些研究者在煤粉着火、不同方式下燃烧特性的光学诊断研究方面主要进展,对煤粉单颗粒和煤粉颗粒流的着火燃烧过程的光学诊断研究进行了总结。目前常用的煤粉燃烧光学诊断技术主要包括:全光谱成像、CH*/C2*化学发光成像、平面激光诱导荧光(PLIF)、双色/三色高温计、米氏散射、激光诱导白炽光、相干反斯托克斯-拉曼光谱、激光诱导击穿光谱等多种先进的光学诊断技术,可对煤粉单颗粒、颗粒流的着火延迟、脱挥发分、挥发分燃烧、着火模式、环境因素(环境温度、氧浓度、气氛)、富氧燃烧、水-氧燃烧、煤中碱金属释放等多方面的关键问题进行光学诊断研究,为煤炭的清洁高效利用提供了理论和实验基础。但目前取得的成果还不够完善,需要继续深入开展煤粉燃烧的光学诊断试验研究,对污染物NOx的生成及排放、新型水氧燃烧技术中水蒸气作用机理等方面深入探索,开发出新型清洁燃烧技术,为我国煤炭资源清洁高效利用做出进一步贡献。

       

      Abstract: Coal,as an important fossil fuel,has abundant reserves. Despite the rapid development of new and renewable energy,coal resources will continue to be an important part of China's primary energy in the coming decades. However,the utilization of coal brings a lot of environmental pollution problems. As a result,the utilization of China ' s coal resources gradually transforms to the high efficiency,low carbon,and low NOxtechnology. With the rapid development of optical diagnostics technology,a variety of in situ non-invasive optical diagnostic techniques that is suitable for pulverized coal combustion diagnosis have emerged,which greatly promotes the development of the combustion science and provides more experimental methods for the clean and efficient utilization of coal. In this paper,the research progress of optical diagnosis on ignition and combustion characteristics of pulverized coal in different ways at home and abroad was introduced. The optical diagnostics research progress on ignition and combustion process of pulverized coal for both single particle and particle streams was summarized. At present,the optical diagnostic techniques used for pulverized coal combustion includes: full spectrum imaging,CH*/C2*chemiluminescence imaging,planar laser induced fluorescence( PLIF),double color/three-color pyrometer,Mie scattering,laser induced incandescence( LII),coherent anti stokes Raman spectroscopy( CARS),laser-induced breakdown spectroscopy( LIBS) and so on.The optical diagnosis research on ignition delay,devolatilization,volatile combustion,ignition mode,environmental factors( ambient temperature,oxygen concentration,atmosphere),oxy-fuel combustion,oxy-steam combustion,the release of alkali metals for both single particle and particle streams was analyzed to provide theoretical and experimental foundation for clean and efficient utilization of coal. The ignition and combustion characteristics of pyrolyzed char and Shenhua bituminous coal blended fuel were studied by using OH-PLIF and three-color pyrometer. Considering the ignition delay and the burnout ratio of the blending,the optimal blending ratio of pyrolyzed char is20%,which provides a reference for actual industrial application of pyrolyzed char. OH-PLIF diagnostic technology with high temporal and spatial resolution of 500 Hz and 5 k Hz were used to investigate the development process of volatiles combustion and the evolution process of volatiles ignition of single particle in pulverized coal particle stream. The time characteristics from ignition to volatiles combustion of pulverized coal particle stream were obtained through the combination of the two. The devolatilization and volatile combustion behavior of pulverized bituminous coal and lignite were investigated with OH-PLIF technology. The relative standard deviation of radial OH signal distribution was used to describe the flame stability. The stability of bituminous coal particle stream combustion is higher than that of lignite under the same combustion conditions. Based on OH-PLIF and CH*chemiluminescence diagnostic techniques,a dynamic mode decomposition method( DMD) was proposed to investigate the combustion oscillation characteristics of volatiles in pulverized coal particle stream.With increase of oxygen concentration,the oscillation of volatile flame is enhanced. The agglomeration of particles may lead to lower frequency oscillation for pulverized coal volatiles combustion. On the contrary,higher oscillation frequency will be produced by individual or separate particle combustion. However,the current achievements are not sufficient. So it is necessary to continue to carry out in-depth research on the optical diagnosis test of pulverized coal combustion,explore the generation and emission of NOxand the mechanism of water vapor in new water-oxygen combustion technology,and develop new clean coal combustion technology,so as to make further contribution to the clean and efficient utilization of Chinese coal resources.

       

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