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    低阶煤热解影响因素及其工艺技术研究进展

    Research progress on influencing factors and technology of low-rank coal pyrolysis

    • 摘要: 我国低阶煤储量巨大,全组分高效利用煤炭资源有助于确保我国能源安全,低阶煤热解可以得到高值化的煤气、焦油以及半焦,实现其高值化梯级利用。本文通过论述低阶煤热解过程的三个阶段阐明了其热解机理,详细阐明包括煤阶、温度、粒径、升温速率、气氛等热解条件以及酸洗、水热、溶胀、离子液体等预处理方法对低阶煤热解反应特性的影响。催化热解通过定向调控获取高品质热解产物,基于催化剂特性的差异和催化行为的不同,分类梳理了不同催化剂对低阶煤催化热解的影响,包括分子筛、过渡金属化合物、碱金属化合物、天然矿石等。在低阶煤热解技术的研究现状和最新进展的基础上,对低阶煤固体热载体、气体热载体以及内构件移动床热解工艺技术进行了总结,并进一步提出了相关展望,加快低阶煤热解技术的发展。

       

      Abstract: There are tremendous reserves of low rank coal resources in China,and the efficient utilization of coal resources can ensure the energy security. High value coal gas,tar and char can be obtained from low rank coal by pyrolysis technology,which achieveshigh value cascade utilization. In this paper,the pyrolysis mechanism of low rank coal was elucidated through three stages of pyrolysis process. In addition,the effects of pyrolysis conditions including coal rank,temperature,particle size,heating rate and atmosphere,and pretreatment methods such as acid washing,hydrothermal treatment,swelling and ionic liquid on pyrolysis reaction of low rank coal were described in detail. Besides,the catalytic pyrolysis of low rank coal is beneficial to high-quality pyrolysis products because of the directional control in pyrolysis process. Based on the differences in catalyst characteristics and catalytic behavior,the effects of different catalysts including molecular sieves,transition metal compounds,alkali metal compounds,and natural ores on the catalytic pyrolysis of low rank coal were classified. On the basis of the research status and latest development of low-rank coal pyrolysis technology,the technology of low rank coal pyrolysis for solid heat carrier,gas heat carrier and moving bed pyrolysis of internal components were summarized,and the further research direction for low rank coal pyrolysis were prospected,so as to provide a theoretical basis for the development of low-rank coal pyrolysis technology.

       

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