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    煤化工VOCs治理技术应用现状及展望

    Application status and prospects of coal chemical VOCs treatment technology

    • 摘要: 煤化工涉及煤的气化、液化、炼焦以及低温干馏等化学工艺,是挥发性有机化合物(VOCs)的重点排放行业。随着我国VOCs减排的深入推进,煤化工VOCs废气的综合治理受到了广泛关注。通过分析煤化工行业VOCs排放源和其排放特征以及主流VOCs治理技术的优缺点,给出具有针对性的VOCs治理技术选择建议。无组织排放VOCs污染防治应从源头控制VOCs泄漏,优化生产技术和改进工艺装备,加强推广气体泄漏与检测(LADR)技术。末端VOCs治理需要综合考虑技术性能、环境性能和经济性能:有回收价值的VOCs废气优先考虑回收技术,回收价值较低或没有回收价值的废气宜采用销毁技术;单一末端治理技术难以有效实现VOCs的减排控制,采用组合技术治理VOCs可以达到更高的净化效率、有效减少二次污染、降低耗能。针对煤制气、煤制焦行业VOCs主要排放源和排放特征的不同,分别给出VOCs治理技术选择建议。通过总结技术研究进展和工业实际应用情况,展望未来研究方向,以期为后续的工业应用选择和深入基础研究提供参考。

       

      Abstract: The coal chemical industry is a typical emission industry of volatile organic compounds( VOCs),involving chemical processes such as gasification,liquefaction,coking,and low-temperature pyrolysis. With the in-depth promotion of VOCs emission reduction action in China,the comprehensive treatment of VOCs exhaust gas from the coal chemical industry has been widely concerned. By analyzing the emission sources and emission characteristics of VOCs in the coal chemical industry and the advantages and disadvantages of mainstream VOCs treatment technologies,some targeted suggestions of VOCs treatment technology were given. According to the differences in the main emission sources and emission characteristics of VOCs in the coal-to-gas and coal-to-coking industries,suggestions on VOCs treatment technology were given respectively. By summarizing the technological research progress and the actual industrial application situation,the future research direction was prospected. At present,the technical system for VOCs emission accounting in the coal chemical industry is imperfect( such as the supplement and adjustment of experience coefficients,localized update of emission coefficients,etc.),the inspection system is imperfect,and the reliability of the test data is insufficient,leading to errors in the accounting results,which seriously affects the fine control of VOCs. Due to the lack of uniform and standardized industry standards,the commonly used " Guidelines for VOCs Pollution in the Petrochemical Industry" is not fully applicable to the coal chemical industry. By optimizing production technology,improving process equipment and strengthening the promotion of LADR technology,the prevention and control of fugitive emission of VOCs should be strictly controlled from the source. The technical performance,economic performance and environmental performance should be considered comprehensively in the treatment of end-point VOCs: VOCs exhaust with recycling value is given priority to use recycling treatment technology,and VOCs exhaust with low recycling value or no recycling value uses destruction treatment technology; single-end treatment technology is difficult to effectively reduce VOCs emissions,and combined technology can achieve higher purification efficiency,effectively reduce secondary pollution and reduce energy consumption. The widely used regenerative catalytic oxidation technology( RCO) has the advantages of strong applicability and good economic benefits,but it is still restricted by the performance of the catalyst. Recently,more and more combined treatment technologies have been proposed and applied,such as adsorption concentration-catalytic combustion,adsorption concentration-regenerative oxidation-adsorption,chemical absorption-photocatalysis-adsorption,chemical absorption-low temperature plasma-photocatalysis,etc. However,the reaction mechanism and interaction of combined governance technologies urgently require to be further studied. For VOCs collection and purification,treatment process,and equipment,coal chemical companies should strengthen fine integrated management,and build a technical system for source control and purification system overall supervision to eliminate human factors.

       

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