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    甲醇水蒸气重整制氢技术进展:催化剂、反应器与人工智能的协同创新

    Advances in Hydrogen Production via Methanol Steam Reforming: Synergistic Innovations in Catalysts, Reactors, and Artificial Intelligence

    • 摘要: 甲醇水蒸气重整制氢(MSR)具有产氢效率高、原料储运便捷及成本低等优势,已成为分布式能源领域的重要制氢途径。本文系统总结了MSR在催化剂、反应器与智能化方面的研究进展。催化剂方面,重点总结了铜基和钯基催化剂的调控机理、载体效应、双金属协同作用及制备方法对MSR的影响。在反应器方面,分析了传统管式反应器的局限,并介绍了微通道反应器在强化传热传质以及膜反应器在产物分离方面的研究现状。在智能化层面,阐述了人工智能技术通过数据驱动方式重构传统研发范式,实现催化剂筛选及反应器结构与运行参数的协同优化,最后,对MSR未来的发展方向进行了展望。

       

      Abstract: Methanol steam reforming (MSR) is widely regarded as an important hydrogen production route for distributed energy systems owing to its high hydrogen yield, convenient storage and transportation of feedstock, and low cost. This paper reviews recent research progress in MSR from the perspectives of catalysts, reactors, and intelligent technologies. In terms of catalysts, the regulation mechanisms of copper-based and palladium-based catalysts are systematically summarized, with emphasis on support effects, bimetallic synergistic interactions, and the influence of preparation methods on MSR performance. Regarding reactor design, the limitations of conventional tubular reactors are analyzed, while the current status of microchannel reactors for enhanced heat and mass transfer and membrane reactors for in-situ product separation is discussed. At the intelligence level, artificial intelligence is shown to reshape traditional research paradigms through data-driven approaches, enabling catalyst screening and the coordinated optimization of reactor structures and operating parameters. Finally, future development directions of MSR are outlined.

       

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