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    煤沥青在锂离子电池负极材料中的应用研究进展

    Research progress on the application of coal tar pitch in negative electrode materials for lithium-ion batteries

    • 摘要: 煤沥青作为一种高碳含量、低成本且来源丰富的煤化工副产品,在开发高性能锂离子电池负极材料方面展现出独特的优势。本文系统综述了煤沥青在锂离子电池负极材料领域的研究进展,首先阐明了基于锂离子在碳基材料中的三种储存机制,通过整合多尺度计算模拟和机器学习算法,可系统揭示碳材料的储锂行为与构效关系;讨论了煤沥青分子组成特征及其对电化学性能的影响规律;随后详细阐述了制备煤沥青基多孔碳的两种主要方法(模板法和活化法),进一步深入探讨了其制备电极的工艺特点与研究进展。其次针对煤沥青基多孔碳在锂离子电池中的实际应用,分析了其在能量存储方面的优势,并指出了规模化应用过程中待解决的关键科学问题。并从材料结构与性能优化的角度,多方面探究了包括孔隙结构调控、表面包覆以及表面化学性质修饰等策略对提升储锂性能的作用机理。最后对煤沥青多孔碳材料的未来发展方向进行了展望,从材料设计理论、电化学机制研究和工艺技术优化等多个维度提出了具有针对性的改进建议,为推动煤沥青基在锂离子电池中的实际应用提供了重要的参考价值。

       

      Abstract: Coal tar pitch, as a high-carbon content, low-cost, and abundantly available byproduct of coal chemical industry, exhibits unique advantages in the development of high-performance anode materials for lithium-ion batteries (LIBs). This paper systematically reviews the research progress of coal tar pitch in the field of LIB anode materials. Firstly, three storage mechanisms based on lithium ions in carbon based materials are elucidated. By integrating multi-scale computational simulations and machine learning algorithms, the lithium storage behavior and structure-activity relationship of carbon materials can be systematically revealed; Discussed the molecular composition characteristics of coal tar pitch and its influence on electrochemical performance; Subsequently, the two main methods for preparing pitch-based porous carbons (template method and activation method) are elaborately described. Furthermore, the characteristic and research progress of electrode preparation using these materials are deeply explored. Focusing on the practical application of pitch-based porous carbons in LIBs, this paper evaluates their advantages in energy storage and identifies key scientific challenges that need to be addressed for scalable applications. Additionally, from the perspectives of material structure and performance optimization, this review systematically discusses strategies such as pore structure modulation, surface coating, and surface chemical property modification, elucidating their mechanisms for enhancing lithium storage performances. Finally, the paper provides a perspective on the future development of pitch-based porous carbons and offers targeted recommendations for improvement in multiple dimensions, including materials design theories, electrochemical mechanism research, and process technology optimization. These insights are expected to provide valuable references for advancing the practical application of coal tar pitch-derived carbon materials in LIBs.

       

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