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    基于自发辐射和吸收信号的氨氢燃烧温度场和NO浓度场重建

    Temperature and NO concentration field reconstruction of ammonia-hydrogen combustion based on spontaneous emission and absorption signals

    • 摘要: 氨气作为一种应用潜力巨大的含氢燃料受到广泛关注,其燃烧温度场和燃烧产物氮氧化物浓度场的实时测量对深入理解氨燃烧机理和控制脱硝工艺中的喷氨量具有重要作用。本文结合自发辐射信号和激光吸收信号分别在燃烧温度场和介质浓度场测量中的优势,开展氨燃烧温度场和NO浓度场测量研究。本文建立了平焰燃烧器火焰模型并模拟了氨气掺氢燃烧状况。不同掺混比例下,其燃烧温度场和水蒸气浓度场具有相似的分布,最高温度随着掺氢比例的增加而下降,燃烧产生主要氮氧化物为NO,NO浓度随着掺氢比例的增加而增加。以模拟结果作为原始温度场和浓度场,利用积分窄谱带比值法(ISBR)重建了不同测量误差下氨氢燃烧的温度场和水蒸气的浓度场。在测量误差为1%时,氨掺氢30%的温度场重建误差为0.53%,H2O浓度场重建误差为2.81%。最后,结合可调谐半导体激光吸收光谱技术(TDLAS),通过选择适合一氧化氮的吸收谱线,重建了一氧化氮的浓度场,并讨论了不同光路下的重建精度。结果表明,在测量误差为1%情况下,布置10条光路时重建误差为2.39%,4条光路则为5.42%,实际应用中可根据精度要求布置适当光路数以降低测量系统复杂度。

       

      Abstract: Ammonia, as a hydrogen containing fuel with great potential for application, has received widespread attention. Real time measurement of its combustion temperature field and nitrogen oxide concentration field of combustion products plays an important role in understanding the mechanism of ammonia combustion and controlling the amount of ammonia injection in denitrification processes. This paper combines the advantages of spontaneous emission signals and laser absorption signals in measuring the combustion temperature field and medium concentration field, respectively, to conduct research on the measurement of ammonia combustion temperature field and NO concentration field. A combustion model for a flat flame burner is established and the combustion of ammonia mixed with hydrogen is simulated. Under different blending ratios, the combustion temperature field and water vapor concentration field have similar distributions. The highest temperature decreases with the increase of hydrogen blending ratio, and the main nitrogen oxide produced by combustion is NO. The concentration of NO increases with the increase of hydrogen blending ratio. The simulation results are used as the original temperature field and concentration field, and the integrated narrow band ratio (ISBR) method is used to reconstruct the temperature field and water vapor concentration field of ammonia hydrogen combustion under different measurement errors. When the measurement error is 1%, the reconstruction error of the temperature field for ammonia hydrogen 30% is 0.53%, and the reconstruction error of the H2O concentration field is 2.81%. Finally, combined with tunable diode laser absorption spectroscopy (TDLAS) technology, the concentration field of NO is reconstructed by selecting suitable absorption lines, and the reconstruction accuracy under different optical paths is discussed. The results show that with a measurement error of 1%, the reconstruction error was 2.39% when 10 optical paths were arranged, and 5.42% when 4 optical paths were arranged. In practical applications, the appropriate number of optical paths can be arranged according to the accuracy requirements to reduce the complexity of the measurement system.

       

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