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    富油煤原位热解渗透率变化机理模拟实验研究

    Simulation experimental investigation on the variation mechanism of permeability during the in-situ pyrolysis of tar-rich coal

    • 摘要: 富油煤渗透率影响地下热解油气运移。本文利用模拟原位条件的实验系统测量了富油煤原位热解过程中的渗透率,通过微型计算机断层扫描(μCT)重构了不同热解条件下富油煤的孔隙-裂隙结构,利用数字岩芯方法建立了富油煤的孔隙-裂隙网络模型,并获取了孔隙-裂隙结构特征参数,最后探究了富油煤孔隙-裂隙结构对渗透率的影响机理。结果表明,在25-300 ℃内富油煤原位脱水、脱气以及热解开裂导致孔隙-裂隙结构特征变化;在300-500 ℃内,富油煤有机质原位热分解改变了孔隙-裂隙结构特征。富油煤原位热解过程中渗透率与孔隙率和最大主裂缝尺寸呈正相关,而与孔喉比和迂曲度呈负相关。原位应力为C4.8&A4.0 MPa(代表围压为4.8 MPa和轴压为4.0 MPa),富油煤在25 ℃时渗透率为5.04 mD,500 ℃时单调增加至95.16 mD。原位应力为C7.7&A6.4 MPa,富油煤在25-300 ℃内渗透率从4.31 mD增加至42.64 mD,500 ℃时降低到26.71 mD。在300-500 ℃内富油煤原位热解反应不仅扩展了孔隙-裂隙结构,而且降低了煤的强度。当富油煤强度小于原位应力时,煤体压缩变形导致孔隙-裂隙闭合,渗透率降低。本研究不仅可为揭示富油煤原位热解油气渗流机理提供理论参考,而且对提高焦油采收率具有工程指导价值。

       

      Abstract: The permeability of tar-rich coal affects the oil and gas transport during the in-situ pyrolysis. In this study, the permeability of tar-rich coal during the in-situ pyrolysis was measured via an experimental system in which the in-situ conditions can be simulated. The pore-fracture structure of tar-rich coal under various in-situ pyrolysis conditions was reconstructed by the μCT. Meanwhile, the pore-fracture network model of tar-rich coal was established by the digital core-reconstruction method. The pore-fracture structure characteristic parameters were finally obtained. Furthermore, the influence mechanism of pore-fracture structure on permeability of tar-rich coal was investigated. The in-situ dehydration, degassing, and pyrolysis cracking of tar-rich coal led to the change in the pore-fracture structure in the temperature range of 25-300 °C. The in-situ thermal decomposition of the organic matter from tar-rich coal led to the change in the pore-fracture structure in the temperature range of 300-500 °C. The permeability of tar-rich coal was positively correlated with the porosity and the maximum main fracture size, and negatively correlated with the pore-throat ratio and the tortuosity during the in-situ pyrolysis. The permeability of tar-rich coal was 5.04 mD at 25 °C and monotonically increased to 95.16 mD at 500 °C under C4.8&A4.0 MPa (representing a confining stress of 4.8 MPa and an axial stress of 4.0 MPa). By contrast, the permeability of tar-rich coal was decreased from 42.64 mD to 26.64 mD at 300-500 °C under C7.7&A6.4 MPa. The in-situ pyrolysis reaction occurred at 300-500 °C, which expanded the pore-fracture structure and reduced the strength of the coal. The compressive deformation of the coal body resulted in the closure of the pore-fracture when the strength of tar-rich coal is less than the in-situ stress, reducing the permeability. This study not only has significant theoretical value in revealing the permeability mechanism during the in-situ pyrolysis of tar-rich coal but also contributes to improving the tar recovery in applications.

       

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