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    有机胺直接空气碳捕集工艺与小型移动式装置开发

    Organic amine direct air carbon capture process and small mobile equipment development

    • 摘要: 直接空气碳捕集(DAC)技术能够选择性捕集空气中的CO2,有利于解决捕集和利用过程中的地域性错位问题。目前,直接空气碳捕集研究主要集中在实验室规模下对捕集性能的探究,并未形成全流程的工艺系统。基于此,研究了伯胺、仲胺和叔胺3种类型胺溶液的CO2捕集和解吸性能,并通过13C核磁共振(NMR)光谱法定性检测吸收剂在捕集和解吸过程中的产物变化,探究了填料类型、填料高度和液气比等操作条件对捕集性能的影响,构建了捕集解吸全流程系统,开发了百升级移动式空气碳捕集集成装置。结果表明:伯胺由于N原子上结合位点较多,能够更快地与CO2反应形成氨基甲酸酯而具有更高的捕集性能,伯胺中异丙醇胺(1A2P)表现出最高的捕集解吸性能。带壁流圈的金属孔板波纹规整填料具有更优异的气液传质性能,且随着填料高度的增加捕集效率逐渐增加,捕集性能随液气比先增加后保持平稳,液气比为100 mL/L时的捕集效率达到了96%。在开发的百升级移动式装置中,运行试验结果显示,吸收塔出口CO2浓度接近0,解吸塔出口CO2浓度可随载气流量大小灵活调节,展现出良好的捕集效率和可操作性。研究构建的全流程DAC系统实现了从实验室研究到小型化应用技术的转化,丰富了直接空气碳捕集的应用场景,为后续规模化发展提供参考。

       

      Abstract: Direct Air Carbon Capture (DAC) technology can selectively capture CO2 from the air, which is conducive to solving the geographical mismatch between capture and utilization. Current research on DAC is mainly focused on the investigation of capture performance at laboratory scale, and there is no full-flow process system. The CO₂ capture and desorption performance of three types of amine solutions (namely primary amine, secondary amine, and tertiary amine) was investigated, and the product changes of the absorber during the capture and desorption processes were qualitatively detected by ¹³C nuclear magnetic resonance (NMR) spectroscopy. The influences of operating conditions such as filler type, filler height, and liquid/gas ratio on the capture process performance were also investigated. A full-process system for capture and desorption was constructed, and an integrated mobile airborne carbon capture equipment with a hundred-ton scale was developed. A mobile airborne carbon capture device was developed. The results show that primary amines have higher capture performance due to the higher number of ratio firstly and then stays stable, and the trapping efficiency with the liquid/gas ratio of 100 mL/L reaches 96%. In binding sites on the N atom, which can react with CO2 to form carbamate faster, and among the primary amines, 1-amino-2-propanol (1A2P) shows the highest capture desorption performance. The metal orifice plate corrugated regular packing with wall flow ring has better gas-liquid mass transfer performance and the trapping efficiency increases gradually with the increase of packing height, and the trapping performance increases with the liquid/gas the developed 100 upgraded mobile equipment, the operation test results show that the CO2 concentration at the outlet of the absorption tower is close to 0, and the CO2 concentration at the outlet of the desorption tower can be flexibly adjusted with the size of the carrier gas flow, which demonstrates the good trapping efficiency and operability. The full-flow DAC system constructed in the study achieves the transformation from laboratory research to miniaturized application technology, enriches the application scenarios of direct air carbon capture, and provides a reference for subsequent scale-up development.

       

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