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    矿井水微絮凝-超滤短流程同步除浊除氟工艺研究

    Study on simultaneous deturbidization and defluoridation of coal mine drainage by microflocculation-ultrafiltration short process

    • 摘要: 针对我国西部地区现有含氟高浊矿井水处理工艺流程长、成本高、效果不稳定等问题,结合高效除氟药剂与特种超滤膜,开发了“微絮凝-超滤”短流程同步除浊除氟新工艺,明晰了同步除浊除氟机理,考察了药剂投加量、搅拌速度、循环流量、跨膜压差等因素对工艺运行的影响,验证了工艺运行稳定性。结果表明,除氟机理主要是由除氟药剂形成的钙-铝-硅酸铁聚合物与游离的F-通过静电吸附、离子交换和络合反应等相互作用生成沉淀去除,该工艺药剂投加量与进水氟离子浓度呈线性相关关系(R2?0.95),最佳搅拌速度80r/min、循环流量10m3/h、跨膜压差为0.25 MPa。并在最佳工艺条件下连续运行85天,除氟除浊效果稳定达标,氟离子浓度可稳定达到《地表水环境质量标准》(GB 3838-2002)III类标准要求的1mg/L以下的氟含量限值,浊度可稳定在1 NTU以下。对比现有的两段法先除浊再吸附除氟工艺,“微絮凝-超滤”工艺具有流程短、占地小、成本低、智慧化程度高、处理效果稳定等优势,可实现含氟高浊矿井水定向高效处理。

       

      Abstract: To address the challenges of long treatment processes, high costs, and unstable performance in treating fluoride-containing high-turbidity coal mine drainage in western China, a novel "micro flocculation-ultrafiltration" process was developed. This short-process technology integrates a highly efficient fluoride removal agent and a specialized ultrafiltration membrane to simultaneously remove turbidity and fluoride. The mechanism for simultaneous turbidity and fluoride removal was elucidated, and the effects of key operational parameters, such as coagulant dosage, stirring speed, circulation flow rate, and transmembrane pressure, on process performance were investigated. The stability of the process was also verified. The results indicate that the primary fluoride removal mechanism involves the interaction of calcium-aluminum-silicon-iron polymers, formed by the fluoride removal agent, with free fluoride ions through electrostatic adsorption, ion exchange, and complexation reactions, resulting in precipitation and removal. The required coagulant dosage was found to be linearly related to the fluoride ion concentration in the influent(R2?0.95). Optimal conditions included a stirring speed of 80 r/min, a circulation flow rate of 10 m3/h, and a transmembrane pressure of 0.25 MPa. Under these conditions, the process operated continuously for 85 days, achieving stable and compliant fluoride and turbidity removal. The fluoride concentration was consistently reduced to below 1 mg/L, meeting the Class III limit of the Environmental Quality Standards for Surface Water (GB 3838-2002), and turbidity was maintained below 1 NTU. Compared to the existing two-stage process that separates turbidity removal and fluoride adsorption, the "micro flocculation-ultrafiltration" process offers advantages such as a shorter treatment flow, smaller footprint, lower cost, higher automation, and more stable performance. This technology enables targeted and efficient treatment of fluoride-containing high-turbidity coal mine drainage.

       

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