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    胺法碳捕集系统吸收塔内传热传质耦合研究及工艺参数优化

    Coupled study of heat and mass transfer in the absorption tower of amine carbon capture system and optimization of process parameters

    • 摘要: 高运行能耗是制约化学吸收法碳捕集技术大规模商业应用的重要因素之一,工艺参数优化是降低再生能耗的有效途径。搭建了吸收塔内CO2吸收传热传质耦合模型,通过对塔内吸收过程进行模拟计算进而优化工艺参数。经Aspen Plus模拟和现场数据结果验证,模型对塔内复杂的传热传质耦合过程具有良好的预测能力。采用MEA吸收剂的碳捕集装置工艺参数优化结果表明:再生能耗随初始贫液负载先降低后略微升高,贫液负载过低会导致再生能耗升高;综合考虑捕集率与再生能耗,当贫液负载为0.207 mol/mol时,吸收塔捕集率为90.04%,再生能耗为3.21 GJ/t(不含节能工艺)。该研究为化学吸收法碳捕集系统吸收塔内复杂传热传质耦合过程探究提供了新方法,对工程实际具有指导意义。

       

      Abstract: High energy consumption is one of the important factors limiting the large-scale commercial application of chemical absorption carbon capture technology, and the optimization of process parameters is an effective way to reduce the regeneration energy consumption. A coupled CO2 absorption heat and mass transfer model is constructed in the absorption tower, and the process parameters are optimized by simulating the absorption process in the tower. Aspen Plus simulation and field data results verify that the model has good prediction ability for the complex heat and mass transfer coupling process in the tower. The optimization results of the process parameters of the carbon capture device using MEA absorber show that: the regeneration energy consumption decreases with the initial lean liquid load and then increases slightly, and too low a lean liquid load will lead to higher regeneration energy consumption; taking the capture rate and regeneration energy consumption into account, the capture rate of the absorption tower is 90.04% and the regeneration energy consumption is 3.21 GJ/t when the lean liquid load is 0.207 mol/mol(excluding energy-saving process). The study provides a new method for the study of the complex heat and mass transfer coupling process in the absorption tower of the chemical absorption carbon capture system, which is of great significance for engineering practice.

       

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