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    超临界水和过热蒸汽作用下的块煤热解试验研究

    Experimental study on pyrolysis of lump coal under the action of supercritical water and superheated steam

    • 摘要: 为了解决传统方法难以有效开发非常规地质资源能源问题和日益加深的环境矛盾问题,采用超临界水和过热蒸汽进行煤原位热解,实现固体煤向可燃气体转化。利用新研制的高温高压反应炉,对块状烟煤进行热解试验研究,探索了超临界水及过热蒸汽对煤热解的影响机制,分析了超临界水和过热蒸汽温度和压力对煤热解产物及热解速率的影响规律。结果表明:超临界水作用下的700 ℃与400 ℃相比,产气量提升了约43倍,在400 ~500 ℃时,产气速率会随着时间的推移不断减缓,二者呈对数关系;当温度升至600~700 ℃,在24 h内并不会随着时间的推移发生反应停止或反应速率减缓的现象,二者呈线性关系,煤以稳定的速率持续不断地析出气体。析出气体中H2的含量提升了29%,CH4含量降低了6%,CO和CO2含量分别降低了10%和12%,失重率提升了22.5%。在水的作用下,压力的改变对煤热解反应的影响较小,仅在达到临界点(温度=374 ℃,压力=22.1 MPa)后,超临界水作用下的煤热解与过热蒸汽相比产气量上升约16%。与过热蒸汽阶段相比,超临界水阶段产气组分以H2为主,CO2与CO的含量减少,CH4含量基本不变,析出气体中H2的含量提升了14%,CO和CO2含量分别降低了3%和13%,失重率提升了3%。研究结果对煤原位流体化开采工艺参数的确定具有重要的参考价值。

       

      Abstract: To address the difficulty of conventional methods in the effective exploitation of unconventional geological resources and energy, as well as the increasingly acute environmental conflicts, an in-situ coal pyrolysis method employing supercritical water and superheated steam was adopted to convert solid coal into combustible gas. Using a newly developed high-temperature and high-pressure reactor, pyrolysis experiments were conducted on lump bituminous coal. The mechanisms by which supercritical water and superheated steam affect coal pyrolysis were investigated, and the influence of temperature and pressure under both conditions on the pyrolysis products and pyrolysis rate of coal was analyzed.The results showed that, under the action of supercritical water, the gas yield at 700 ℃ was approximately 43 times higher than that at 400 ℃. At 400–500 ℃, the gas production rate continuously decreased with time, exhibiting a logarithmic relationship. When the temperature rose to 600–700 ℃, no reaction termination or rate deceleration occurred within 24 h; the two showed a linear relationship, and the coal continuously released gas at a stable rate. In the released gas, the H2 content increased by 29%, the CH4 content decreased by 7%, the CO and CO2 contents decreased by 10% and 12% respectively, and the weight loss rate increased by 20%.Under the action of water, changes in pressure had little effect on the coal pyrolysis reaction. Only after reaching the critical point (temperature = 374 ℃, pressure = 22.1 MPa) did the gas yield under supercritical water exceed that under superheated steam by about 16%. Compared with the superheated steam stage, the gas components produced in the supercritical water stage were dominated by H2, with reduced CO2 and CO contents and essentially unchanged CH4 content. Specifically, the H2 content in the released gas increased by 14%, the CO and CO2 contents decreased by 3% and 13% respectively, and the weight loss rate increased by 3%. The research findings provide important reference value for determining the process parameters of in-situ coal fluidized mining.

       

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